Organic Letters
2008-10-16
Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides.
Laurence Caron, Louis-Charles Campeau, Keith Fagnou
文献索引:Org. Lett. 10 , 4533, (2008)
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摘要
Direct arylation reactions of nitrobenzenes and aryl halides occur in good yield and high ortho regioselectivity. These reactions can be performed on gram scale with as few as 3 equiv of the nitro arene relative to the aryl halide. The synthetic utility of this method is demonstrated via rapid synthesis of a Boscalid intermediate.
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