Organic & Biomolecular Chemistry 2011-04-21

Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.

Christian Bukovec, Uli Kazmaier

文献索引：Org. Biomol. Chem. 9 , 2743-2750, (2011)

全文：HTML全文

摘要

Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized building blocks in excellent yields.

相关化合物

  • 氨基钠

相关文献：

Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2.

2014-12-14

[Dalton Trans. 43(46) , 17324-32, (2014)]

Isotopic studies of the ammonia decomposition reaction mediated by sodium amide.

2015-09-21

[Phys. Chem. Chem. Phys. 17 , 22999-3006, (2015)]

M. Bakavoli, et al.,

[J. Heterocycl. Chem. 48 , 149-152, (2010)]

C. Caubere, et al.,

[Tetrahedron 50 , 11903-11920, (1994)]

K. G. Hampton, et al.,

[Organic Synth. 51 , 128-132, (1971)]

更多文献...