Glycosylation of l,4:3,6-dianhydro-D-glucitol (isosorbide).
David J Claffey, Mary F Casey, Patrick A Finan
文献索引:Carbohydr. Res. 339 , 2433-2440, (2004)
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摘要
Condensation of 2,3,4,6-tetra-O-acetyl-alpha-D-glucopyranosyl-, 2,3,4-tri-O-acetyl-alpha-D-xylopyranosyl- and of 2,3,4,6-tetra-O-acetyl-alpha-D-galactopyranosyl bromides with l,4:3,6-dianhydro-D-glucitol under Koenigs-Knorr conditions, and using the Helferich modification of the reaction showed regioselectivity in glysosylation at C-5 of isosorbide.
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