Journal of the American Chemical Society
2012-02-01
Cis-selective ring-opening metathesis polymerization with ruthenium catalysts.
Benjamin K Keitz, Alexey Fedorov, Robert H Grubbs
文献索引：J. Am. Chem. Soc. 134 , 2040-2043, (2012)
全文：HTML全文
摘要
Cis-selective ring-opening metathesis polymerization of several monocyclic alkenes as well as norbornene and oxanorbornene-type monomers using a C-H activated, ruthenium-based metathesis catalyst is reported. The cis content of the isolated polymers depended heavily on the monomer structure and temperature. A cis content as high as 96% could be obtained by lowering the temperature of the polymerization.© 2012 American Chemical Society
相关化合物
相关文献：
2012-01-11
[J. Am. Chem. Soc. 1st ed., 134 , 693-699, (2012)]