Organic Letters
2005-11-24
Enantioselective synthesis of furo[2,3-b]furans, a spongiane diterpenoid substructure.
Roland Weisser, Weimin Yue, Oliver Reiser
文献索引:Org. Lett. 7(24) , 5353-6, (2005)
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摘要
[structure: see text] A short and enantioselective synthesis of cis-fused 5-oxofuro[2,3-b]furans, being found in many spongiane diterpenoid natural products, is reported starting from inexpensive methyl 2-furoate. Moreover, the acid-catalyzed rearrangement of the furo[2,3-b]furan framework A to B is observed for some derivatives, suggesting a simple connection between natural products differing in the absolute configuration of the 3a,6a ring junction.
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2013-07-05
[Org. Lett. 15(13) , 3420-3, (2013)]