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4-硝基氯化苄

4-硝基氯化苄用途

【用途一】
用于有机合成
【用途二】
用作医药中间体
【用途三】
alpha-Chloro-p-nitrotoluene

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4-硝基氯化苄名称

[ CAS 号 ]:
100-14-1

[ 中文名 ]:
1-(氯甲基)-4-硝基苯

[ 英文名 ]:
4-Nitrobenzyl chloride

[中文别名 ]:

对硝基氯苄

[英文别名 ]:

α-Chloro-4-nitrotoluene
Benzene, 1- (chloromethyl)-4-nitro-
Toluene, α-chloro-p-nitro-
α-Chloro-p-nitrotoluene
EINECS 202-822-7
MFCD00007374
4-Nitrobenzyl chloride
Benzene, 1-(chloromethyl)-4-nitro-
1-(Chloromethyl)-4-nitrobenzene

4-硝基氯化苄物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
292.5±15.0 °C at 760 mmHg

[ 熔点 ]:
71 °C

[ 分子式 ]:
C₇H₆ClNO₂

[ 分子量 ]:
171.581

[ 闪点 ]:
130.7±20.4 °C

[ 精确质量 ]:
171.008713

[ PSA ]:
45.82000

[ LogP ]:
2.22

[ 外观性状 ]:
淡黄色结晶粉末

[ 蒸汽压 ]:
0.0±0.6 mmHg at 25°C

[ 折射率 ]:
1.574

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类、食品添加剂分开存放

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents, bases, amines, moisture, alcohols. Corrodes steel. Reacts slowly with water. Combustible.

4-硝基氯化苄MSDS

4-硝基氯化苄毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XS9093000

CHEMICAL NAME :: Toluene, alpha-chloro-p-nitro-

CAS REGISTRY NUMBER :: 100-14-1

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C7-H6-Cl-N-O2

MOLECULAR WEIGHT :: 171.59

WISWESSER LINE NOTATION :: WNR D1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1809 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 280 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 20 mg/m3/6H/2W-I

TOXIC EFFECTS :: Nutritional and Gross Metabolic - weight loss or decreased weight gain Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 100 umol/L

REFERENCE :: JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 3,203,1983

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4-硝基氯化苄安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R22;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3261 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
XS9093000

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
2904909090

4-硝基氯化苄合成路线

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4-硝基氯化苄上游产品

4-硝基氯化苄下游产品

4-硝基氯化苄海关

[ 海关编码 ]: 2904909090

[ 中文概述 ]:
2904909090 其他烃的磺化、硝化、亚硝化衍生物（不论是否卤化）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

4-硝基氯化苄文献

A heme model system for the reduction of substrates by microsomal cytochrome P 450.

Biochem. Biophys. Res. Commun. 104(4) , 1651-7, (1982)

A case of multiple sensitization to three halogeno-substituted mono-nitrobenzenes.

Ital. Gen. Rev. Dermatol. 15(2) , 107-12, (1978)

A case of occupational contact dermatitis in a female chemical pharmaceutical laboratory researcher is described. The allergological investigation revealed a state of sensitization to three mono-nitro...

Hepatic and branchial glutathione S-transferases of two fish species: substrate specificity and biotransformation of microcystin-LR.

Comp. Biochem. Physiol. C. Toxicol. Pharmacol. 149(4) , 515-23, (2009)

Liver and gills of roach (Rutilus rutilus) and silver carp (Hypophthalmichthys molitrix) were examined for glutathione S-transferases (GSTs) contents and their substrate specificity and capacity to bi...

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