乙苯_MSDS_用途_密度_乙苯CAS号【100-41-4】

【用途一】
用作苯乙烯的原料，也用于制药和其他有机合成
【用途二】
用作色谱标准物质和溶剂，也用于有机合成
【用途三】
乙苯主要用于生产苯乙烯，进而生产苯乙烯均聚物以及以苯乙烯为主要成分的共聚物（ABS，AS等）。乙苯少量用于有机合成工业，例如生产苯乙酮、乙基蒽醌、对硝基苯乙酮、甲基苯基甲酮等中间体。在医药上用作合霉素和氯霉素的中间体。也用于香料。此外，还可作溶剂使用。
【用途四】
乙苯主要用于生产苯乙烯，进而生产苯乙烯均聚物以及以苯乙烯为主要成分的共聚物（ABS，AS等）。乙苯少量用于有机合成工业，例如生产苯乙酮、乙基蒽醌、对硝基苯乙酮、甲基苯基甲酮等中间体。在医药上用作合霉素和氯霉素的中间体。也用于香料。此外，还可作溶剂使用。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。

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[ 密度 ]:
0.865

[ 沸点 ]:
136 °C at 760 mmHg

[ 熔点 ]:
−95 °C(lit.)

[ 分子式 ]:
C₈H₁₀

[ 分子量 ]:
106.165

[ 闪点 ]:
22.2±0.0 °C

[ 精确质量 ]:
106.078247

[ LogP ]:
3.21

[ 外观性状 ]:
无色液体

[ 蒸汽密度 ]:
3.7 (vs air)

[ 蒸汽压 ]:
9.2±0.1 mmHg at 25°C

[ 折射率 ]:
1.497

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 稳定性 ]:
Stable. Incompatible with oxidizing agents. Flammable.

[ 水溶解性 ]:
0.0206 g/100 mL

[ 凝固点 ]:
-95℃

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DA0700000

CHEMICAL NAME :: Benzene, ethyl-

CAS REGISTRY NUMBER :: 100-41-4

LAST UPDATED :: 199712

DATA ITEMS CITED :: 62

MOLECULAR FORMULA :: C8-H10

MOLECULAR WEIGHT :: 106.18

WISWESSER LINE NOTATION :: 2R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human

DOSE/DURATION :: 100 ppm/8H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - sleep Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3500 mg/kg

TOXIC EFFECTS :: Liver - other changes Kidney, Ureter, Bladder - other changes

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4000 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 50 gm/m3/2H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2624 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 17800 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 10000 ppm

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - lacrimation Behavioral - tremor

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 740 ppm/6H/92D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 782 ppm/6H/4W-I

TOXIC EFFECTS :: Liver - changes in liver weight Blood - changes in leukocyte (WBC) count Blood - changes in platelet count

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 975 ppm/6H/97D-I

TOXIC EFFECTS :: Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 782 ppm/6H/4W-I

TOXIC EFFECTS :: Liver - changes in liver weight

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 mg/m3/4H/30W-I

TOXIC EFFECTS :: Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Blood - other changes Blood - changes in leukocyte (WBC) count

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 97 ppm/7H

SEX/DURATION :: female 15 day(s) pre-mating

TOXIC EFFECTS :: Reproductive - Fertility - female fertility index (e.g. # females pregnant per # sperm positive females; # females pregnant per # females mated)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 985 ppm/7H

SEX/DURATION :: female 1-19 day(s) after conception

TOXIC EFFECTS :: Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 96 ppm/7H

SEX/DURATION :: female 1-19 day(s) after conception

TOXIC EFFECTS :: Reproductive - Specific Developmental Abnormalities - musculoskeletal system

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 600 mg/m3/24H

SEX/DURATION :: female 7-15 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - musculoskeletal system

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 2400 mg/m3/24H

SEX/DURATION :: female 7-15 day(s) after conception

TOXIC EFFECTS :: Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 99 ppm/7H

SEX/DURATION :: female 1-18 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 500 mg/m3/24H

SEX/DURATION :: female 7-20 day(s) after conception

TOXIC EFFECTS :: Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 1 gm/m3/24H

SEX/DURATION :: female 7-20 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - abortion

MUTATION DATA

TYPE OF TEST :: Micronucleus test

TEST SYSTEM :: Rodent - hamster Embryo

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 392,61,1997 *** REVIEWS *** ACGIH TLV-STEL 543 mg/m3 (125 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 434 mg/m3 (100 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 100 ppm (435 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,104,1971 OSHA PEL (Gen Indu):8H TWA 100 ppm (435 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 100 ppm (435 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 100 ppm (435 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 100 ppm (435 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 100 ppm (435 mg/m3);STEL 125 ppm (545 mg/m3) JAN 1993 OEL-BELGIUM:TWA 100 ppm (434 mg/m3);STEL 125 ppm (543 mg/m3) JAN 1993 OEL-DENMARK:TWA 50 ppm (217 mg/m3) JAN 1993 OEL-FINLAND:TWA 100 ppm (435 mg/m3);STEL 150 ppm (655 mg/m3) JAN 1993 OEL-FRANCE:TWA 100 ppm (435 mg/m3) JAN 1993 OEL-GERMANY:TWA 100 ppm (440 mg/m3);Skin JAN 1993 OEL-HUNGARY:TWA 100 mg/m3;STEL 200 mg/m3;Skin JAN 1993 OEL-JAPAN:TWA 100 ppm (430 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 100 ppm (435 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 100 ppm (435 mg/m3) JAN 1993 OEL-POLAND:TWA 100 mg/m3 JAN 1993 OEL-RUSSIA:TWA 100 ppm;STEL 50 mg/m3 JAN 1993 OEL-SWEDEN:TWA 50 ppm (200 mg/m3);STEL 100 ppm (450 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 100 ppm (435 mg/m3);STEL 500 ppm JAN 1993 OEL-TURKEY:TWA 100 ppm (435 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 100 ppm (435 mg/m3);STEL 125 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ETHYL BENZENE-air:10H TWA 100 ppm;STEL 125 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 31830 No. of Facilities: 7190 (estimated) No. of Industries: 64 No. of Occupations: 55 No. of Employees: 57442 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 31830 No. of Facilities: 17633 (estimated) No. of Industries: 126 No. of Occupations: 92 No. of Employees: 201833 (estimated) No. of Female Employees: 34405 (estimated)

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[ 符号 ]:

GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H315-H319-H331-H351-H361d-H372

[ 警示性声明 ]:
P260-P280-P304 + P340 + P312-P305 + P351 + P338-P403 + P233

[ 靶器官 ]:
Missing Phrase - TD-124117

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;Xn:Harmful;

[ 风险声明 (欧洲) ]:
R11;R20

[ 安全声明 (欧洲) ]:
S9-S16-S29-S33-S24/25-S36/37-S36-S45-S36/37/39-S26-S23-S53-S7-S24

[ 危险品运输编码 ]:
UN 1175 3/PG 2

[ WGK德国 ]:
1

[ RTECS号 ]:
KI5775000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
2902600000

乙苯上游产品

乙苯下游产品

4.液相烷基化法通常是在常压、85-90℃下，采用三氯化铝为催化剂，使乙烯与苯反应生成乙苯。副反应是乙苯进上步被乙烯烷基化生成多乙苯。工业上将苯的转化率限制在52-55%在右，并采用高的苯-乙烯摩尔比（一般为2左右），以防止生成更的二乙苯与多乙苯。乙苯的平均收率为94-96%。

5.气相烷基化法最初是乙烯和过量的苯在磷酸-硅藻土上蔌氧化铝-硅胶催化剂作用下，于300℃、4-6兆帕下进行气相烷基化反应制取乙苯。由于所采用的催化剂不能进行多乙苯的脱烷基，故多乙苯无法处理。虽然通过增加苯的配料比减少多乙苯的生成，但却增加了循环苯的蒸馏成本。

6.由C8芳烃分离制乙苯催化重整所制得的芳烃。经分离除去苯和甲苯后，混合二甲苯馏分各组分的沸点很接近，用精馏的方法分离乙苯需用300-400块塔板，回流比为75。另外也可采用吸附分离和色层分离理到乙苯。由于从C8芳烃分离乙苯在经济上已无法与苯烷基化乙苯相竞争，并且新一代贵金属异构化催化剂能有效地将乙苯转化成二甲苯，从而使乙苯分离的重要性大大下降。

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[ 海关编码 ]: 2902600000

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公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐乾明

产品详情：乙基苯

公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥58.0/500ml

联系人：刘佳

产品详情：乙基苯

公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥需询单/1mg ￥需询单/1g ￥需询单/1g ￥需询单/1g

联系人：阿拉丁

产品详情：乙基苯

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详细MSDS(安全技术说明书)

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ACUTE TOXICITY DATA

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