氯亚铂酸钾
氯亚铂酸钾用途
制备其它铂化合物的重要原料
【用途二】
用作分析试剂
【用途三】
制备其它贵金属化合物和催化剂的重要原料.
氯亚铂酸钾名称
[ CAS 号 ]:
10025-99-7
[ 中文名 ]:
氯亚铂酸钾
[ 英文名 ]:
Potassium tetrachloroplatinate(II)
[中文别名 ]:
[英文别名 ]:
- EINECS 233-050-9
- dipotassium,tetrachloroplatinum(2-)
- Dipotassium tetrachloroplatinate(2-)
- Potassium platinochloride
- Platinate(2-), tetrachloro-, potassium (1:2)
- Potassium tetrachloroplatinate
- Platinous potassium chloride
- Potasium tetrachloroplatinate (I)
- Potassium tetrachloroplatinate(II)
- Potassium chloroplatinite
氯亚铂酸钾物理化学性质
[ 密度 ]:
3.38 g/mL at 25 °C(lit.)
[ 熔点 ]:
250°C
[ 分子式 ]:
Cl4K2Pt
[ 分子量 ]:
415.08700
[ 精确质量 ]:
412.76800
[ LogP ]:
2.75550
[ 外观性状 ]:
红色结晶固体
[ 储存条件 ]:
室温,干燥,密封
[ 稳定性 ]:
Stable. Incompatible with acids, strong oxidizing agents.
[ 水溶解性 ]:
10 g/L (20 ºC)
氯亚铂酸钾MSDS
氯亚铂酸钾毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TP1850000
- CHEMICAL NAME :
- Platinate(2-), tetrachloro-, dipotassium
- CAS REGISTRY NUMBER :
- 10025-99-7
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 34
- MOLECULAR FORMULA :
- Cl4-Pt.2K
- MOLECULAR WEIGHT :
- 415.09
- WISWESSER LINE NOTATION :
- KA2 PT-G4
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Human - child
- DOSE/DURATION :
- 400 mg/kg
- TOXIC EFFECTS :
- Cardiac - other changes
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Human - man
- DOSE/DURATION :
- 8571 ug/kg
- TOXIC EFFECTS :
- Gastrointestinal - gastritis Kidney, Ureter, Bladder - renal function tests depressed Blood - eosinophilia
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intradermal
- SPECIES OBSERVED :
- Human
- DOSE/DURATION :
- 40 mg/kg
- TOXIC EFFECTS :
- Skin and Appendages - primary irritation (after topical exposure) Skin and Appendages - corrosive (after topical exposure)
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 45 mg/kg
- TOXIC EFFECTS :
- Tumorigenic - active as anti-cancer agent
MUTATION DATA
- TYPE OF TEST :
- Mutation in mammalian somatic cells
- TEST SYSTEM :
- Rodent - hamster Ovary
- DOSE/DURATION :
- 65 umol/L
- REFERENCE :
- CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 40,1463,1980 *** REVIEWS *** ACGIH TLV-TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,213,1971 OSHA PEL (Gen Indu):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.002 mg(Pt)/m3 (dust) JAN 1993 OEL-AUSTRALIA:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-BELGIUM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-DENMARK:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-FINLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-GERMANY:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-HUNGARY:STEL 0.002 mg(Pt)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
氯亚铂酸钾安全信息
[ 符号 ]:
GHS05, GHS06, GHS08
[ 信号词 ]:
Danger
[ 危害声明 ]:
H301-H315-H317-H318-H334
[ 警示性声明 ]:
P261-P280-P301 + P310-P305 + P351 + P338-P342 + P311
[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
T:Toxic;
[ 风险声明 (欧洲) ]:
R25;R38;R41;R42/43
[ 安全声明 (欧洲) ]:
S22-S26-S36/37/39-S45
[ 危险品运输编码 ]:
UN 3288 6.1/PG 3
[ WGK德国 ]:
1
[ RTECS号 ]:
TP1850000
[ 包装等级 ]:
I; II; III
[ 危险类别 ]:
6.1
[ 海关编码 ]:
2922509090
氯亚铂酸钾合成路线
氯亚铂酸钾上下游产品
氯亚铂酸钾上游产品
氯亚铂酸钾下游产品
氯亚铂酸钾制备
将二氯化铂溶于盐酸,即形成四氯合铂(Ⅱ)酸,加入氯化钾,用冰水冷却而得。
氯亚铂酸钾海关
[ 海关编码 ]: 2922509090
[ 中文概述 ]:
2922509090. 其他氨基醇酚、氨基酸酚及其他含氧基氨基化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB. 最惠国关税:6.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装
[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单
[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验
[ Summary ]:
2922509090. other amino-alcohol-phenols, amino-acid-phenols and other amino-compounds with oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
氯亚铂酸钾文献
Eur. J. Med. Chem. 89 , 77-87, (2014)
A new platinum(II) complex of [Pt(II)(L) (pn)]Cl·2H2O (1) (pn = 1,3-propanediamine) with 2-(4-methoxy-phenyl)imidazo [4,5-f]-[1,10]phenanthrolin (H-L) was synthesized and characterized. In complex 1, ...
Monofunctional Platinum-containing Pyridine-based Ligand Acts Synergistically in Combination with the Phytochemicals Curcumin and Quercetin in Human Ovarian Tumour Models.Anticancer Res. 35 , 2783-94, (2015)
With the idea that platinum compounds that bind with DNA differently than cisplatin may be better-able to overcome platinum resistance in ovarian tumor, the monofunctional platinum complex tris(imidaz...
Platinum complexes and pyruvate kinase activity.Gen. Physiol. Biophys. 17(1) , 25-36, (1998)
The interaction of platinum complexes with bovine heart pyruvate kinase (PK) was studied by absorption, CD, fluorescence spectroscopy and enzymic activity test. Our results showed that activity of PK ...
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产品详情:氯亚铂酸钾(四氯铂酸钾)
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相关化合物
【氯亚铂酸钾】化源网提供氯亚铂酸钾CAS号10025-99-7,氯亚铂酸钾MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询氯亚铂酸钾上化源网,专业又轻松。>>电脑版:氯亚铂酸钾
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