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氯亚铂酸钾

氯亚铂酸钾用途

【用途一】
制备其它铂化合物的重要原料
【用途二】
用作分析试剂
【用途三】
制备其它贵金属化合物和催化剂的重要原料.

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氯亚铂酸钾名称

[ CAS 号 ]:
10025-99-7

[ 中文名 ]:
氯亚铂酸钾

[ 英文名 ]:
Potassium tetrachloroplatinate(II)

[中文别名 ]:

[英文别名 ]:

EINECS 233-050-9
dipotassium,tetrachloroplatinum(2-)
Dipotassium tetrachloroplatinate(2-)
Potassium platinochloride
Platinate(2-), tetrachloro-, potassium (1:2)
Potassium tetrachloroplatinate
Platinous potassium chloride
Potasium tetrachloroplatinate (I)
Potassium tetrachloroplatinate(II)
Potassium chloroplatinite

氯亚铂酸钾物理化学性质

[ 密度 ]:
3.38 g/mL at 25 °C(lit.)

[ 熔点 ]:
250°C

[ 分子式 ]:
Cl₄K₂Pt

[ 分子量 ]:
415.08700

[ 精确质量 ]:
412.76800

[ LogP ]:
2.75550

[ 外观性状 ]:
红色结晶固体

[ 储存条件 ]:
室温，干燥，密封

[ 稳定性 ]:
Stable. Incompatible with acids, strong oxidizing agents.

[ 水溶解性 ]:
10 g/L (20 ºC)

氯亚铂酸钾MSDS

氯亚铂酸钾毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TP1850000

CHEMICAL NAME :: Platinate(2-), tetrachloro-, dipotassium

CAS REGISTRY NUMBER :: 10025-99-7

LAST UPDATED :: 199712

DATA ITEMS CITED :: 34

MOLECULAR FORMULA :: Cl4-Pt.2K

MOLECULAR WEIGHT :: 415.09

WISWESSER LINE NOTATION :: KA2 PT-G4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Human - child

DOSE/DURATION :: 400 mg/kg

TOXIC EFFECTS :: Cardiac - other changes

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Human - man

DOSE/DURATION :: 8571 ug/kg

TOXIC EFFECTS :: Gastrointestinal - gastritis Kidney, Ureter, Bladder - renal function tests depressed Blood - eosinophilia

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intradermal

SPECIES OBSERVED :: Human

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Skin and Appendages - primary irritation (after topical exposure) Skin and Appendages - corrosive (after topical exposure)

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 45 mg/kg

TOXIC EFFECTS :: Tumorigenic - active as anti-cancer agent

MUTATION DATA

TYPE OF TEST :: Mutation in mammalian somatic cells

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 65 umol/L

REFERENCE :: CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 40,1463,1980 *** REVIEWS *** ACGIH TLV-TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,213,1971 OSHA PEL (Gen Indu):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.002 mg(Pt)/m3 (dust) JAN 1993 OEL-AUSTRALIA:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-BELGIUM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-DENMARK:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-FINLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-GERMANY:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-HUNGARY:STEL 0.002 mg(Pt)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

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氯亚铂酸钾安全信息

[ 符号 ]:

GHS05, GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H315-H317-H318-H334

[ 警示性声明 ]:
P261-P280-P301 + P310-P305 + P351 + P338-P342 + P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R25;R38;R41;R42/43

[ 安全声明 (欧洲) ]:
S22-S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3288 6.1/PG 3

[ WGK德国 ]:
1

[ RTECS号 ]:
TP1850000

[ 包装等级 ]:
I; II; III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2922509090

氯亚铂酸钾合成路线

氯亚铂酸钾上下游产品

氯亚铂酸钾上游产品

氯亚铂酸钾下游产品

氯亚铂酸钾制备

将二氯化铂溶于盐酸，即形成四氯合铂(Ⅱ)酸，加入氯化钾，用冰水冷却而得。

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氯亚铂酸钾海关

[ 海关编码 ]: 2922509090

[ 中文概述 ]:
2922509090. 其他氨基醇酚、氨基酸酚及其他含氧基氨基化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件：AB. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验

[ Summary ]:
2922509090. other amino-alcohol-phenols, amino-acid-phenols and other amino-compounds with oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

氯亚铂酸钾文献

Synthesis of a platinum(II) complex with 2-(4-methoxy-phenyl) imidazo [4,5-f]-[1,10] phenanthrolin and study of its antitumor activity.

Eur. J. Med. Chem. 89 , 77-87, (2014)

A new platinum(II) complex of [Pt(II)(L) (pn)]Cl·2H2O (1) (pn = 1,3-propanediamine) with 2-(4-methoxy-phenyl)imidazo [4,5-f]-[1,10]phenanthrolin (H-L) was synthesized and characterized. In complex 1, ...

Monofunctional Platinum-containing Pyridine-based Ligand Acts Synergistically in Combination with the Phytochemicals Curcumin and Quercetin in Human Ovarian Tumour Models.

Anticancer Res. 35 , 2783-94, (2015)

With the idea that platinum compounds that bind with DNA differently than cisplatin may be better-able to overcome platinum resistance in ovarian tumor, the monofunctional platinum complex tris(imidaz...

Platinum complexes and pyruvate kinase activity.

Gen. Physiol. Biophys. 17(1) , 25-36, (1998)

The interaction of platinum complexes with bovine heart pyruvate kinase (PK) was studied by absorption, CD, fluorescence spectroscopy and enzymic activity test. Our results showed that activity of PK ...

更多文献

氯亚铂酸钾

氯亚铂酸钾用途

氯亚铂酸钾名称

氯亚铂酸钾物理化学性质

氯亚铂酸钾MSDS

详细MSDS(安全技术说明书)

氯亚铂酸钾毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

氯亚铂酸钾安全信息

氯亚铂酸钾合成路线

详细合成路线

氯亚铂酸钾上下游产品

氯亚铂酸钾上游产品

氯亚铂酸钾下游产品

氯亚铂酸钾制备

氯亚铂酸钾海关

氯亚铂酸钾文献

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