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四氯化锡

四氯化锡用途

【用途一】
用作分析试剂和媒染剂
【用途二】
有机合成脱水剂，织物媒染剂。

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四氯化锡名称

[ CAS 号 ]:
10026-06-9

[ 中文名 ]:
结晶四氯化锡

[ 英文名 ]:
Stannic chloride pentahydrate

[中文别名 ]:

四氯化锡五水合物

[英文别名 ]:

Tin(IV) chloride pentahydrate
Tetrachlorostannane pentahydrate
MFCD00149864
tin(iv) tetrachloride pentahydrate
EINECS 231-588-9
Stannane, tetrachloro-, hydrate (1:5)
tetrachlorostannane,pentahydrate

四氯化锡物理化学性质

[ 沸点 ]:
114.1ºC at 760 mmHg

[ 熔点 ]:
56 °C

[ 分子式 ]:
H₁₀Cl₄O₅Sn

[ 分子量 ]:
350.598

[ 精确质量 ]:
349.830444

[ PSA ]:
46.15000

[ LogP ]:
2.05570

[ 外观性状 ]:
白色至黄色固体

[ 蒸汽压 ]:
23.9mmHg at 25°C

[ 储存条件 ]:
库房通风低温干燥,与碱分开存放

[ 稳定性 ]:
Stable, but may decompose in contact with moisture or water. Incompatible with strong acids.

[ 水溶解性 ]:
soluble

四氯化锡MSDS

详细MSDS(安全技术说明书)

四氯化锡毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XP8870000

CAS REGISTRY NUMBER :: 10026-06-9

LAST UPDATED :: 199712

DATA ITEMS CITED :: 24

MOLECULAR FORMULA :: Cl4-Sn.5H2-O

MOLECULAR WEIGHT :: 350.59

WISWESSER LINE NOTATION :: .SN-G4.QH5

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 120 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 32 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Human Lymphocyte

DOSE/DURATION :: 2 mg/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 282,61,1992 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 2 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,257,1971 OSHA PEL (Gen Indu):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Sn)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Sn)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Sn)/m3 JAN 1993 OEL-FINLAND:TWA 2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 2 mg(Sn)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(Sn)/m3;STEL 2 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Sn)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2 mg(Sn)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Sn)/m3;STEL 4 mg(Sn)/m3 JAN 1993 OEL-THAILAND:TWA 2 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Sn)/m3;STEL 10 mg(Sn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9720 No. of Facilities: 18 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 108 (estimated) No. of Female Employees: 72 (estimated)

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四氯化锡安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ 危害码 (欧洲) ]:
C: Corrosive;

[ 风险声明 (欧洲) ]:
R34;R52/53

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S7/8-S61

[ 危险品运输编码 ]:
UN 2440 8/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
XP8870000

[ 包装等级 ]:
III

[ 危险类别 ]:
8

四氯化锡制备

1.由无水四氯化锡缓慢地加入到水中，得到的热溶液在搅拌下冷却结晶制得。或者将氯气通入二氯化锡溶液中至饱和，加热蒸发，再冷却结晶，分离制得。

2.向33mL水中分次少量地逐渐加入100g无水氯化锡，溶解时剧烈放热，所得透明液体在搅拌和冷却下即可全部结晶。产量100～103g，产率约85%。

3.将干燥的氯气通到装有金属锡粒的带有冷凝器的容器底部，进行反应：

反应比较激烈，放出的热量使四氯化锡发进入冷凝器，待反应结束后，将四氯化锡倒回反应器，密封静置1h，让过量锡与游离氯结合，然后将溶液蒸馏，收集112～114℃馏分，得无水四氯化锡。在搅拌下将所得四氯化锡溶解到适当蒸馏水中（100g四氯化锡用33ml水），溶解时大量放热，待透明热溶液冷却至完全结晶，即为结晶四氯化锡。

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四氯化锡文献

Sharp, S.L. et al.

Chem. Mater. 10 , 880, (1998)

Condensations of benzil with phenols and aryl ethers mediated by tin (IV) chloride pentahydrate. Morrison BJ and Musgrave OC.

Tetrahedron 58(21) , 4255-4260, (2002)

Preparation of hard agglomerates free and weakly agglomerated antimony doped tin oxide (ATO) nanoparticles by coprecipitation reaction in methanol reaction medium. Kim DW, et al.

Mater. Chem. Phys. 97(2) , 452-457, (2006)

更多文献

四氯化锡

四氯化锡用途

四氯化锡名称

四氯化锡物理化学性质

四氯化锡MSDS

详细MSDS(安全技术说明书)

四氯化锡毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

四氯化锡安全信息

四氯化锡制备

四氯化锡文献

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