N,N-二仲丁基对苯二胺

N,N-二仲丁基对苯二胺用途

是性能优良的胺类抗氧剂，在多种石油产品中起到优异的抗氧化效果。具有优异的自由基和脱硫性能。广泛应用于矿物油、加氢油、合成油和植物油等。
本品属性能优良的胺类抗氧剂，特别适合用作裂解或热裂解法汽油（高烯烃含量汽油）添加剂，能有效阻止烯烃氧化产生凝胶，从而避免油品使用过程中在燃烧室、活塞顶、汽缸盖等部位产生积炭，与其他胺类抗氧剂相比，本品用量少、抗氧化效果好，大大减少环境污染。此外，本品还可用作天然胶、合成胶的通用型抗氧剂。

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N,N-二仲丁基对苯二胺名称

[ CAS 号 ]:
101-96-2

[ 中文名 ]:
N,N-二仲丁基对苯二胺

[ 英文名 ]:
N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine

[中文别名 ]:

N,N'-二仲丁基对苯二胺

[英文别名 ]:

N,N'-Di-sec-butyl-p-phenylenediamine
N,N′-Di-sec-butyl-p-phenylenediamine
1,4-Benzenediamine, N,N-bis(1-methylpropyl)-
N,N'-Di(butan-2-yl)benzene-1,4-diamine
EINECS 202-992-2
NN'-Di-sec-butyl-p-phenylenediamine
N,N'-bis(1-methylpropyl)benzene-1,4-diamine
N,N'-Di-sec-butyl-1,4-benzenediamine
N,N'-Di-sec-butylbenzene-1,4-diamine
NN'-Bis(1-methylpropyl)-1,4-phenylenediamine

N,N-二仲丁基对苯二胺物理化学性质

[ 密度 ]:
0.942

[ 沸点 ]:
343.2±25.0 °C at 760 mmHg

[ 熔点 ]:
17.8°C

[ 分子式 ]:
C₁₄H₂₄N₂

[ 分子量 ]:
220.354

[ 闪点 ]:
192.6±14.9 °C

[ 精确质量 ]:
220.193954

[ PSA ]:
24.06000

[ LogP ]:
3.39

[ 外观性状 ]:
琥珀色至红色或暗微红的黑色液体

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.539

[ 储存条件 ]:
室温

[ 稳定性 ]:
正常温度和压力下稳定

[ 水溶解性 ]:
<0.1 g/100 mL at 20 ºC

N,N-二仲丁基对苯二胺MSDS

详细MSDS(安全技术说明书)

N,N-二仲丁基对苯二胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SS9040000

CHEMICAL NAME :: p-Phenylenediamine, N,N'-di-sec-butyl-

CAS REGISTRY NUMBER :: 101-96-2

BEILSTEIN REFERENCE NO. :: 2805827

LAST UPDATED :: 199801

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C14-H24-N2

MOLECULAR WEIGHT :: 220.40

WISWESSER LINE NOTATION :: 2Y1&MR DMY2&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 148 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Gastrointestinal - other changes Kidney, Ureter, Bladder - other changes in urine composition

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 600 mg/m3/6H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2806 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Kidney, Ureter, Bladder - other changes in urine composition Skin and Appendages - dermatitis, other (after systemic exposure)

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555010

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: RCTEA4 Rubber Chemistry and Technology. (American Chemical Soc., Rubber Division, c/o Mrs. M.E. Bauer, Univ. of Akron, Akron, OH 44325) V.1- 1928- Volume(issue)/page/year: 45,627,1972

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 10 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: IPSTB3 International Polymer Science and Technology. (Rapra Technology Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year: 3,93,1976 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6950 No. of Facilities: 184 (estimated) No. of Industries: 3 No. of Occupations: 11 No. of Employees: 9196 (estimated) No. of Female Employees: 257 (estimated)

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N,N-二仲丁基对苯二胺安全信息

[ 符号 ]:

GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H315-H317-H318-H410

[ 警示性声明 ]:
P273-P280-P301 + P310 + P330-P305 + P351 + P338 + P310-P333 + P313

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R25;R34;R43;R50/53

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S61

[ 危险品运输编码 ]:
UN 2922 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
SS9040000

[ 包装等级 ]:
III

[ 危险类别 ]:
第8.2类碱性腐蚀品(国内暂不属于危险化学品范畴)

[ 海关编码 ]:
2921519090

N,N-二仲丁基对苯二胺合成路线

详细合成路线

N,N-二仲丁基对苯二胺上下游产品

N,N-二仲丁基对苯二胺上游产品

N,N-二仲丁基对苯二胺下游产品

N,N-二仲丁基对苯二胺海关

[ 海关编码 ]: 2921519090

[ 中文概述 ]:
2921519090. 间-、对-苯二胺、二氨基甲苯等〔包括衍生物及它们的盐〕. 增值税率:17.0%. 退税率:17.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921519090. o-, m-, p-phenylenediamine, diaminotoluenes, and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%