硝酸铈
硝酸铈用途
用作分析试剂及催化剂
【用途二】
可用作磷酸酯水解反应的催化剂,用于制汽灯纱罩、光学玻璃等
【用途三】
可用作汽灯纱罩添加剂、石油化工催化剂,是制取铈盐的原料。分析化学中用作分析试剂,也用于制药工业。
【用途四】
用于钨钼制品(铈钨电极、镧钨电极),三元催化剂, 汽灯纱罩添加剂,硬质合金难熔金属等其它工业。
硝酸铈名称
[ CAS 号 ]:
10294-41-4
[ 中文名 ]:
硝酸铈(III) 六水合物
[ 英文名 ]:
CERIUM(III) NITRATE HEXAHYDRATE
[中文别名 ]:
[英文别名 ]:
- EINECS 233-297-2
- Cerium nitrate hexahydrate
- Cerium(3+) nitrate hydrate (1:3:6)
- cerium(3+),trinitrate,hexahydrate
- MFCD00149631
硝酸铈物理化学性质
[ 密度 ]:
4.37
[ 沸点 ]:
200°C
[ 熔点 ]:
96℃
[ 分子式 ]:
H12CeN3O15
[ 分子量 ]:
434.222
[ 精确质量 ]:
433.932281
[ PSA ]:
262.02000
[ LogP ]:
0.46650
[ 外观性状 ]:
无色液体
[ 储存条件 ]:
库房低温通风干燥
[ 稳定性 ]:
Stable. Hygroscopic and air sensitive. Oxidizing. Incompatible with strong reducing agents, strong bases.
硝酸铈MSDS
硝酸铈毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- FK6300000
- CAS REGISTRY NUMBER :
- 10294-41-4
- LAST UPDATED :
- 199406
- DATA ITEMS CITED :
- 7
- MOLECULAR FORMULA :
- N3-O9.Ce.6H2-O
- MOLECULAR WEIGHT :
- 434.27
- WISWESSER LINE NOTATION :
- CE N-O3*3 &QH 6
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 12,615,1993
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 12,615,1993 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 4200 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 290 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 4 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 470 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 5,750,1963 *** REVIEWS *** TOXICOLOGY REVIEW JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 54,663,1965
硝酸铈安全信息
[ 符号 ]:
GHS03, GHS05, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H272-H318-H410
[ 警示性声明 ]:
P210-P273-P280-P305 + P351 + P338 + P310-P370 + P378-P501
[ 个人防护装备 ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
Xi: Irritant;
[ 风险声明 (欧洲) ]:
R8
[ 安全声明 (欧洲) ]:
S17-S26-S39
[ 危险品运输编码 ]:
UN 1477 5.1/PG 2
[ WGK德国 ]:
2
[ RTECS号 ]:
FK6300000
[ 包装等级 ]:
III
[ 危险类别 ]:
5.1
[ 海关编码 ]:
2846109090
硝酸铈制备
1.硝酸法将富铈氢氧化稀土酸性溶液,水解,硝酸溶解,在草酸或过氧化氢存在下使4价铈还原成3价铈,再经结晶、分离,制得硝酸铈成品。
2.将草酸铈在水浴上加热溶于稀硝酸,过滤,将滤液蒸发,浓缩冷却结晶。
硝酸铈海关
[ 海关编码 ]: 2846109090
硝酸铈文献
J. Antimicrob. Chemother. 70 , 1083-93, (2015)
The objective of this study was to clarify the antifungal properties of cerium, a lanthanide member, against Candida species. A comprehensive study with planktonic and sessile cells was performed. The...
Enhancing electrochemical performance by control of transport properties in buffer layers--solid oxide fuel/electrolyser cells.Phys. Chem. Chem. Phys. 17(17) , 11527-39, (2015)
The current work demonstrates how tailoring the transport properties of thin ceria-based buffer layers in solid oxide fuel or electrolyser cells can provide the necessary phase stability against chemi...
Catalytic hydrodechlorination of trichloroethylene in a novel NaOH/2-propanol/methanol/water system on ceria-supported Pd and Rh catalysts.J. Environ. Manage. 158 , 1-10, (2015)
The catalytic hydrodechlorination (HDC) of high concentrations of trichloroethylene (TCE) (4.9 mol%, 11.6 vol%) was studied over 1%Pd, 1%Rh and 0.5%Pd-0.5%Rh catalysts supported on CeO2 under conditio...
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相关化合物
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