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高氯酸铜

高氯酸铜名称

[ CAS 号 ]:
10294-46-9

[ 中文名 ]:
高氯酸铜六水合物

[ 英文名 ]:
copper(ii) perchlorate hexahydrate

[中文别名 ]:

高氯酸铜

[英文别名 ]:

copper,diperchlorate,hexahydrate
EINECS 237-391-4
MFCD00149666
Copper(II) perchlorate hexahydrate

高氯酸铜物理化学性质

[ 密度 ]:
2.225 g/mL at 25 °C(lit.)

[ 沸点 ]:
120°C

[ 熔点 ]:
82°C

[ 分子式 ]:
Cl₂CuH₁₂O₁₄

[ 分子量 ]:
370.53900

[ 精确质量 ]:
368.89000

[ PSA ]:
203.92000

[ LogP ]:
0.04030

[ 折射率 ]:
1.505

[ 储存条件 ]:
室温，密封

[ 水溶解性 ]:
每100毫升水中的溶解克数: 146g/30℃

高氯酸铜MSDS

详细MSDS(安全技术说明书)

高氯酸铜安全信息

[ 符号 ]:

GHS03, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H272-H315-H319-H335

[ 警示性声明 ]:
P220-P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
O:Oxidizing;Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38;R8

[ 安全声明 (欧洲) ]:
S17-S26-S36

[ 危险品运输编码 ]:
UN 1481 5.1/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
II

[ 危险类别 ]:
5.1

高氯酸铜制备

把过量的（5mL）无水高氯酸在-80℃加到大约2g无水硝酸铜中（用干冰冷却）。此时没有反应发生。缓慢温热到0℃以下时开始反应，反应混合物体积增大。在室温下过夜。把混合物再冷却到-80℃，抽真空除去过量的高氯酸，可以缓慢温热到室温。抽真空24h，混合物重量增加。在真空下加热到110℃直至恒重，得淡蓝色晶体。

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高氯酸铜文献

Fluorescent mixed ligand copper(II) complexes of anthracene-appended Schiff bases: studies on DNA binding, nuclease activity and cytotoxicity.

Dalton Trans. 44 , 11997-2010, (2015)

A series of mixed ligand copper(ii) complexes of the type [Cu(L)(phen)(ACN)](ClO4)21-5, where L is a bidentate Schiff base ligand (N(1)-(anthracen-10-ylmethylene)-N(2)-methylethane-1,2-diamine (L1), N...

Mixed ligand copper(II) complexes of 1,10-phenanthroline with tridentate phenolate/pyridyl/(benz)imidazolyl Schiff base ligands: covalent vs non-covalent DNA binding, DNA cleavage and cytotoxicity.

J. Inorg. Biochem. 140 , 255-68, (2014)

A series of copper(II) complexes of the types [Cu(L)(phen)](ClO4) 1-2, where HL is a tridentate ligand with two nitrogen and one oxygen donor atoms (2NO) such as 2-(2-(1H-benzimidazol-2-yl)ethyliminom...

Homeotropic orientation behavior of nematic liquid crystals induced by copper ions.

Colloids Surf. B Biointerfaces 130 , 287-91, (2015)

A homeotropic ordering film of nematic liquid crystal (LC) induced by copper ions (Cu(2+)) had been developed. The Cu(ClO4)2 was directly spin-coated on the glass substrate without any other chemical ...

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