丙烯
丙烯用途
用途二：用作聚丙烯的原料
用途三：丙烯是重要的化工原料。丙烯气相氧化得到的丙烯醛，用于生产丙烯酸、烯丙醇、甘油醛、羟基乙醛以及重要的食品和饲料添加剂蛋氨酸；丙烯氨氧化得到的丙烯腈是合成纤维、合成橡胶和塑料的重要原料；丙烯氯化得到的氯丙烯可进而合成烯丙醇、丙烯二氯丙醇、氯丙腈等，用于生甘油、环氧树脂、氯醇橡胶、表面活笥剂等；丙烯烷基化得到异丙苯，是目前苯酚的主要中间体，在生产苯酚同时联产丙酮；丙烯经羰基合成得正丁醛和异丁醛，可衍生许多有机合成中间体，用于增塑剂、染料、溶剂、农药等；丙烯水合得到异丙醇，用于生产丙酮、用于生产丙酮、异丙胺及异丙酯；丙烯二聚得到乙烯、三聚得到千烯、聚合得到聚丙烯，丙烯四聚得到的十二碳烯是表面活性剂的中间体。
丙烯名称
[ CAS 号 ]:
115-07-1
[ 中文名 ]:
丙烯
[ 英文名 ]:
PROPYLENE
[英文别名 ]:
- propylene radical cation
- oxetene
- PROPYLENE
- MFCD00009279
- EINECS 204-062-1
丙烯物理化学性质
[ 密度 ]:
1.49
[ 沸点 ]:
−47.7 °C(lit.)
[ 熔点 ]:
−185 °C(lit.)
[ 分子式 ]:
C3H6
[ 分子量 ]:
42.07970
[ 闪点 ]:
-108 °C
[ 精确质量 ]:
42.04700
[ LogP ]:
1.19230
[ 外观性状 ]:
无色气体
[ 蒸汽密度 ]:
1.48 (vs air)
[ 蒸汽压 ]:
15.4 atm ( 37.7 °C)
[ 折射率 ]:
1.3567
[ 储存条件 ]:
库房通风低温干燥,轻装轻卸,与氧气、空气等助燃气体钢瓶分开存放
[ 稳定性 ]:
Stable. Highly flammable. Readily forms explosive mixtures with air. Incompatible with strong oxidizing agents, strong acids, halogens.
[ 凝固点 ]:
-185.25℃
丙烯MSDS
丙烯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UC6740000
- CHEMICAL NAME :
- Propene
- CAS REGISTRY NUMBER :
- 115-07-1
- LAST UPDATED :
- 199801
- DATA ITEMS CITED :
- 25
- MOLECULAR FORMULA :
- C3-H6
- MOLECULAR WEIGHT :
- 42.09
- WISWESSER LINE NOTATION :
- 2U1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LC - Lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >86 gm/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 60,161,1994 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 5000 ppm/6H/2Y-I
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 76,288,1984
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1250 ppm/6H/14W-I
- TOXIC EFFECTS :
- Related to Chronic Data - death
- REFERENCE :
- NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NTP-TR-272,1985 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Simple asphyxiant, NO TWA DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 19,213,1979 IARC Cancer Review:Animal No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 19,213,1979 IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 60,161,1994 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 60,161,1994 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 60,161,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:Asphyxiant JAN 1993 OEL-BELGIUM:Asphyxiant JAN 1993 OEL-HUNGARY:Asphyxiant JAN 1993 OEL-THE NETHERLANDS:Asphyxiant JAN 1993 OEL-RUSSIA:STEL 100 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 10000 ppm (17500 mg/m3) JAN 1993 OEL-UNITED KINGDOM:Asphyxiant JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 63495 No. of Facilities: 493 (estimated) No. of Industries: 16 No. of Occupations: 32 No. of Employees: 7150 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 63495 No. of Facilities: 162 (estimated) No. of Industries: 7 No. of Occupations: 25 No. of Employees: 7305 (estimated) No. of Female Employees: 975 (estimated)
丙烯安全信息
[ 危害码 (欧洲) ]:
F+:Extremely flammable
[ 风险声明 (欧洲) ]:
R12
[ 安全声明 (欧洲) ]:
S9-S16-S33
[ 危险品运输编码 ]:
UN 1077 2.1
[ WGK德国 ]:
-
[ RTECS号 ]:
UC6740000
[ 危险类别 ]:
2.1
[ 海关编码 ]:
2901220000
丙烯合成路线
丙烯上下游产品
丙烯上游产品
丙烯下游产品
丙烯制备
1.炼厂催化裂化气经蒸馏除去C2和C4馏分，得到丙烯、丙烷馏分，再经精馏得丙烯。
2.石油烃类经高温裂解的产物，是乙烯生产的联产品。
3.丙烷脱氢。催化剂为氧化铬氧化铝，反应温度635℃，丙烷转化率54%，丙烯选择性76%，回收率93%（分子比）。
4.采用吸附膨胀脱附法，从吸附相得到高纯丙烯产品。以工业丙烯为原料，粗纯化后经分子筛吸附剂选择性吸附，对极性化合物和不饱和烃选择吸附性强，在升温解吸过程中，比丙烯难吸附的组分易入气相馏出，然后从吸附相中得到高纯丙烯产品。
丙烯海关
[ 海关编码 ]: 2901220000
[ 中文概述 ]:
2901220000 丙烯。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最低关税:2.0%。普通关税:20.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 用作气体燃料的应报明包装容器容积, 散装货物应报明
[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单
[ 检验检疫 ]: M.进口商品检验 N.出口商品检验
[ Summary ]:
2901220000 prop-1-ene。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:2.0%。general tariff:20.0%
相关化工产品/化学物质：
推荐生产厂家/供应商：
相关化合物
【丙烯】化源网提供丙烯CAS号115-07-1，丙烯MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询丙烯上化源网，专业又轻松。>>电脑版：丙烯
标题：丙烯_MSDS_用途_密度_丙烯CAS号【115-07-1】_化源网 地址：https://m.chemsrc.com/mip/cas/115-07-1_165170.html