六氟丙烯
六氟丙烯用途
可制备多种含氟精细化工产品、药物中间体、灭火剂等，还可制得含氟高分子材料
【用途二】
该品是合成含氟高分子材料（如氟橡胶F20-41、F246和氟塑料F46等）的单体之一。还可用于全氟磺酸离子交换膜（用于食盐电解）、氟碳油和全氟环氧丙烷等的原料。
六氟丙烯名称
[ CAS 号 ]:
116-15-4
[ 中文名 ]:
六氟丙烯
[ 英文名 ]:
Hexafluoropropylene
[中文别名 ]:
[英文别名 ]:
- CF3CF=CF2
- HEXAFLUOROPROPENE
- hexafluoro-propen
- MFCD00000447
- hexafluoro-propylen
- Hexafluofoproene
- PERFLUOROPROPYLENE
- Perfluoro-1-propene
- EINECS 204-127-4
- PERFLUOROPROPENE
六氟丙烯物理化学性质
[ 密度 ]:
1,583 g/cm3
[ 沸点 ]:
−28 °C(lit.)
[ 熔点 ]:
−153 °C(lit.)
[ 分子式 ]:
C3F6
[ 分子量 ]:
150.02300
[ 精确质量 ]:
149.99000
[ LogP ]:
2.62630
[ 外观性状 ]:
无色气体
[ 蒸汽压 ]:
4770mmHg at 25°C
[ 折射率 ]:
1.5478 (17.5ºC)
[ 储存条件 ]:
库房通风低温干燥,轻装轻卸,与易燃物分开存放
[ 稳定性 ]:
Stable. Incompatible with alkali metals, powdered metals.
六氟丙烯MSDS
六氟丙烯毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- UD0350000
- CHEMICAL NAME :
- Propene, hexafluoro-
- CAS REGISTRY NUMBER :
- 116-15-4
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 11
- MOLECULAR FORMULA :
- C3-F6
- MOLECULAR WEIGHT :
- 150.03
- WISWESSER LINE NOTATION :
- FYFUYFXFFF
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 11200 mg/m3/4H
- TOXIC EFFECTS :
- Behavioral - muscle contraction or spasticity
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 15(2),38,1971
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 750 ppm/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. (SPPIF, B.P.22, F-41353 Vineuil, France) V.7- 1946- Volume(issue)/page/year: 27,509,1966 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1120 ug/m3/4H/34D-I
- TOXIC EFFECTS :
- Kidney, Ureter, Bladder - changes in bladder weight
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 15(2),38,1971
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 150 ppm/6H/90D-I
- TOXIC EFFECTS :
- Behavioral - fluid intake Blood - changes in other cell count (unspecified) Nutritional and Gross Metabolic - changes in sodium
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0522814
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 150 ppm/6H/90D-I
- TOXIC EFFECTS :
- Behavioral - fluid intake Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0522814 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - T0174 No. of Facilities: 28 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 224 (estimated)
六氟丙烯安全信息
[ 危害码 (欧洲) ]:
Xn:Harmful;
[ 风险声明 (欧洲) ]:
R20;R37
[ 安全声明 (欧洲) ]:
S41
[ 危险品运输编码 ]:
UN 1858 2.2
[ WGK德国 ]:
1
[ RTECS号 ]:
UD0350000
[ 危险类别 ]:
2.2
[ 海关编码 ]:
2903391000
六氟丙烯合成路线
六氟丙烯上下游产品
六氟丙烯上游产品
六氟丙烯下游产品
六氟丙烯制备
由四氟乙烯热裂解而得。将四氟乙烯通入高温裂解炉在700℃裂化，裂化气经除酸、干燥、压缩后进行粗馏，馏出物冷冻、脱气，最后精馏得到成品。
六氟丙烯海关
[ 海关编码 ]: 2903399090
[ 中文概述 ]:
2903399090. 其他无环烃的氟化、溴化或碘化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2903399090. brominated,fluorinated or iodinated derivatives of acyclic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
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