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二甲基烯丙基二磷酸三铵盐

二甲基烯丙基二磷酸三铵盐用途

DMAPP(二甲基烯丙基焦磷酸盐)三氨是一种类异戊二烯前体。DMAPP三氨作为异戊烯基焦磷酸盐(IPP)的异构体,几乎存在于所有生命形式中[1]。

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二甲基烯丙基二磷酸三铵盐名称

[ CAS 号 ]:
1186-30-7

[ 中文名 ]:
二甲基丙烯基二磷酸-三铵盐

[ 英文名 ]:
DMAPP

[中文别名 ]:

二甲基烯丙基二磷酸三铵盐

[英文别名 ]:

DIMETHYLALLYL PYROPHOSPHATE TRIAMMONIUM SALT
IPP
MFCD00189839
D-ERYTHRO-2-TETRADECANOYLAMINO-1-PHENYL-1-PROPANOL
ISOPENTENYL PYROPHOSPHATE TRIAMMONIUM SALT
ISOPENTENYL PYROPHOSPHATE AMMONIUM SALT
dimethylallyl diphosphate

二甲基烯丙基二磷酸三铵盐生物活性

[ 描述 ]:

DMAPP(二甲基烯丙基焦磷酸盐)三氨是一种类异戊二烯前体。DMAPP三氨作为异戊烯基焦磷酸盐(IPP)的异构体,几乎存在于所有生命形式中[1]。

[ 相关类别 ]:

信号通路 >> 其他 >> 其他

研究领域 >> 代谢疾病

[体外研究]

DMAPP三氨是一种类异戊二烯前体。DMAPP三氨是类异戊二烯前体生物合成的甲羟戊酸途径和甲羟戊酸途径的产物。DMAPP三氨是异戊烯基焦磷酸盐(IPP)的同分异构体,几乎存在于所有生命形式中。异戊烯基焦磷酸异构酶催化DMAPP和IPP之间的异构化[1]

[参考文献]

[1]. Wang W, et al. Bioorganometallic chemistry with IspG and IspH: structure, function, and inhibition of the [Fe(4)S(4)] proteins involved in isoprenoid biosynthesis. Angew Chem Int Ed Engl. 2014;53(17):4294-4310.

二甲基烯丙基二磷酸三铵盐物理化学性质

[ 沸点 ]:
550.8ºC at 760 mmHg

[ 分子式 ]:
C₅H₂₁N₃O₇P₂

[ 分子量 ]:
297.184

[ 闪点 ]:
21ºC

[ 精确质量 ]:
297.085480

[ PSA ]:
141.40000

[ LogP ]:
3.62210

[ 外观性状 ]:
液体

[ 蒸汽压 ]:
1.38E-13mmHg at 25°C

[ 储存条件 ]:
20°C

二甲基烯丙基二磷酸三铵盐MSDS

详细MSDS(安全技术说明书)

二甲基烯丙基二磷酸三铵盐安全信息

[ 符号 ]:

GHS02, GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H301 + H311 + H331-H370

[ 警示性声明 ]:
P210-P260-P280-P301 + P310-P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S7

[ 危险品运输编码 ]:
UN 1230 3/PG 2

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二甲基烯丙基二磷酸三铵盐文献

Coupling limonene formation and oxyfunctionalization by mixed-culture resting cell fermentation.

Biotechnol. Bioeng. 112 , 1738-50, (2015)

Metabolic engineering strategies mark a milestone for the fermentative production of bulk and fine chemicals. Yet, toxic products and volatile reaction intermediates with low solubilities remain chall...

Cloning and characterization of farnesyl pyrophosphate synthase from the highly branched isoprenoid producing diatom Rhizosolenia setigera.

Sci. Rep. 5 , 10246, (2015)

The diatom Rhizosolenia setigera Brightwell produces highly branched isoprenoid (HBI) hydrocarbons that are ubiquitously present in marine environments. The hydrocarbon composition of R. setigera vari...

Characterization of the xiamenmycin biosynthesis gene cluster in Streptomyces xiamenensis 318.

PLoS ONE 9(6) , e99537, (2014)

Xiamenmycin (1) is a prenylated benzopyran derivative with anti-fibrotic activity. To investigate the genetic basis of xiamenmycin biosynthesis, we performed genome mining in the xiamenmycin-producing...

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