吡螨胺

吡螨胺用途

【用途一】
高效、快速酰胺类杀螨剂，具有独特的化学性质和作用方式，无交互抗性，对各种螨类和螨的发育全过程均有速效高效、持效期长、毒性低、无内吸性（有渗透性）特性。对蚜虫、叶蝉、粉虱等半翅目害虫也有一定防效，主要用于棉花、果树、蔬菜、茶树等作物。推荐浓度20～200mg/L。
【用途二】
属酰胺类杀螨剂，对各种螨类和半翅目、同翅目害虫有卓效，而且对螨类各生长期均有速效和高效，持效期长。

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吡螨胺名称

[ CAS 号 ]:
119168-77-3

[ 中文名 ]:
吡螨胺

[ 英文名 ]:
Tebufenpyrad

[中文别名 ]:

[英文别名 ]:

MFCD01632408
T5NNJ A1 C2 DG EVM1R DX1&1&1
Tebufenpyrad

吡螨胺物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
468.4±45.0 °C at 760 mmHg

[ 熔点 ]:
61-62ºC

[ 分子式 ]:
C₁₈H₂₄ClN₃O

[ 分子量 ]:
333.856

[ 闪点 ]:
237.1±28.7 °C

[ 精确质量 ]:
333.160797

[ PSA ]:
46.92000

[ LogP ]:
3.90

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 折射率 ]:
1.565

[ 储存条件 ]:
库房低温,通风,干燥

吡螨胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UQ6276400

CHEMICAL NAME :: 1H-Pyrazole-5-carboxamide, 4-chloro-N-((4-(1,1-dimethylethyl)phenyl)methyl)-3-et hyl-1-methyl-

CAS REGISTRY NUMBER :: 119168-77-3

LAST UPDATED :: 199710

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C18-H24-Cl-N3-O

MOLECULAR WEIGHT :: 333.90

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 595 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AGJAEP Agrochemcicals Japan. (Japan Plant Protection Association, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.62- 1993- Volume(issue)/page/year: (64),12,1994

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2660 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AGJAEP Agrochemcicals Japan. (Japan Plant Protection Association, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.62- 1993- Volume(issue)/page/year: (64),12,1994

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AGJAEP Agrochemcicals Japan. (Japan Plant Protection Association, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.62- 1993- Volume(issue)/page/year: (64),12,1994

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吡螨胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S36

[ 危险品运输编码 ]:
2588

[ RTECS号 ]:
UQ6276400

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2933199012

吡螨胺制备

1、草酸二乙酯与丁酮反应得丙酰丙酮酸乙酯，以乙醇或甲苯为溶剂，控制温度0℃，有利于反应进行；再与水合肼环合生成3-乙基-吡唑-5-羧酸乙酯，反应温度15℃，时间2h，产物用氯仿萃取；再用（CH3）2SO4甲基化，得3-乙基-1-甲基吡唑-5-羧酸乙酯，以氯仿为溶剂，室温滴加甲基化剂，40℃反应2h；再经氯化硫酰处理，制得4-氯-3-乙基-1-甲基吡唑-5-羧酸乙酯，升温回流反应3h；再加NaOH水解，加热回流5h，加盐酸调节pH值2～3，析出固体；再与SOCl2作用，使羧基变为酰氯基；最后在氯仿、三乙胺存在下与叔丁基苄胺作用，得吡螨胺。

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吡螨胺海关

[ 海关编码 ]: 2933199012

吡螨胺文献

First detection of chlorfenapyr (Secure) resistance in two-spotted spider mite (Acari: Tetranychidae) from nectarines in an Australian orchard.

Exp. Appl. Acarol. 31(1-2) , 131-4, (2003)

Chlorfenapyr resistance (2.9- and 19.9-fold respectively at LC50 and LC99 level) was detected in Tetranychus urticae Koch causing control failure following a single application of product to nectarine...

New developments in insecticide resistance in the glasshouse whitefly (Trialeurodes vaporariorum) and the two-spotted spider mite (Tetranychus urticae) in the UK.

Pest Manag. Sci. 58(2) , 123-30, (2002)

A recent survey of insecticide resistance in two of the most problematic pests in UK glasshouses revealed some new developments. At least some individuals in all UK samples of Trialeurodes vaporarioru...

Ultraviolet radiation increases sensitivity to pesticides: synergistic effects on population growth rate of Daphnia magna at low concentrations.

Bull. Environ. Contam. Toxicol. 87(3) , 231-7, (2011)

In the present study we aimed to investigate whether UV-B radiation can exacerbate effects of pesticides fenoxycarb, pirimicarb, and tebufenpyrad on the survival, reproduction, and population growth r...

更多文献

吡螨胺

吡螨胺用途

吡螨胺名称

吡螨胺物理化学性质

吡螨胺毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

吡螨胺安全信息

吡螨胺制备

吡螨胺海关

吡螨胺文献

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