二氯二茂铌
二氯二茂铌名称
[ CAS 号 ]:
12793-14-5
[ 中文名 ]:
二氯二茂铌
[ 英文名 ]:
cyclopenta-1,3-diene,cyclopentane,dichloroniobium
[英文别名 ]:
- MFCD00009949
二氯二茂铌物理化学性质
[ 分子式 ]:
C10H10Cl2Nb
[ 分子量 ]:
293.99900
[ 精确质量 ]:
292.92200
[ LogP ]:
3.42200
[ 外观性状 ]:
棕色固体
二氯二茂铌MSDS
二氯二茂铌毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- QU0400000
- CHEMICAL NAME :
- Niobium, dichlorobis(eta(sup 5)-2,4-cyclopentadien-1-yl)-
- CAS REGISTRY NUMBER :
- 12793-14-5
- LAST UPDATED :
- 198209
- DATA ITEMS CITED :
- 1
- MOLECULAR FORMULA :
- C10-H10-Cl2-Nb
- MOLECULAR WEIGHT :
- 294.01
- WISWESSER LINE NOTATION :
- G-NB-GR&R
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 35 mg/kg
- TOXIC EFFECTS :
- Behavioral - changes in motor activity (specific assay) Skin and Appendages - hair Tumorigenic - active as anti-cancer agent
- REFERENCE :
- JINCAO Journal of Inorganic and Nuclear Chemistry. (Oxford, UK) V.1-43, 1955-81. Volume(issue)/page/year: 42,1789,1980
二氯二茂铌安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H315-H319-H335
[ 警示性声明 ]:
P261-P305 + P351 + P338
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xi: Irritant;
[ 风险声明 (欧洲) ]:
R36/37/38
[ 安全声明 (欧洲) ]:
26-36
[ 危险品运输编码 ]:
NONH for all modes of transport
[ RTECS号 ]:
QU0400000
[ 海关编码 ]:
2903890090
二氯二茂铌合成路线
二氯二茂铌上下游产品
二氯二茂铌上游产品
二氯二茂铌下游产品
二氯二茂铌海关
[ 海关编码 ]: 2903890090
[ 中文概述 ]:
2903890090. 其他环烷烃、环烯烃或环萜烯烃的卤化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
二氯二茂铌文献
J. Inorg. Biochem. 86(2-3) , 611-6, (2001)
The interaction of the antitumor active metallocene dihalides Cp(2)MCl(2) (M=Ti, Nb, Mo) and 1 equiv. of glutathione was studied by (1)H NMR spectroscopy at pD 2-7 in 4 mM NaCl solutions. No interacti...
Organometallic anticancer agents. 2. Aqueous chemistry and interaction of niobocene dichloride with nucleic acid constituents and amino acids.J. Med. Chem. 39(25) , 5012-6, (1996)
The solution chemistry and interactions of niobocene dichloride, Cp2NbCl2, with nucleosides, nucleotides, and amino acids has been studied by 1H and 31P NMR spectroscopy. The 1H NMR spectrum of Cp2NbC...
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