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2,4,7-三硝基-9-芴酮

2,4,7-三硝基-9-芴酮用途

用于制造炸药，用作化学试剂。

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2,4,7-三硝基-9-芴酮名称

[ CAS 号 ]:
129-79-3

[ 中文名 ]:
2,4,7-三硝基芴酮

[ 英文名 ]:
9H-Fluoren-9-one,2,4,7-trinitro-

[中文别名 ]:

[英文别名 ]:

2,4,7-trinitrofluorene-9-one
9H-Fluoren-9-one,2,4,7-trinitro
2,4,7-Trinitro-9-fluorenone
EINECS 204-965-0
trinitrofluorenone
2,3-DIMETHYL-4'-PIPERIDINOMETHYL BENZOPHENONE
2,4,7-Trinitrofluorenone
2,4,7-Trinitrofluorone
MFCD00001142
2,4,7-Trinitro-9H-fluoren-9-one

2,4,7-三硝基-9-芴酮物理化学性质

[ 密度 ]:
1.747 g/cm3

[ 沸点 ]:
561.7ºC at 760 mmHg

[ 熔点 ]:
176-178ºC

[ 分子式 ]:
C₁₃H₅N₃O₇

[ 分子量 ]:
315.19500

[ 闪点 ]:
292.3ºC

[ 精确质量 ]:
315.01300

[ PSA ]:
154.53000

[ LogP ]:
4.19220

[ 蒸汽压 ]:
1.2E-12mmHg at 25°C

[ 折射率 ]:
1.751

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放

2,4,7-三硝基-9-芴酮MSDS

2,4,7-三硝基-9-芴酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: LL9100000

CHEMICAL NAME :: Fluoren-9-one, 2,4,7-trinitro-

CAS REGISTRY NUMBER :: 129-79-3

LAST UPDATED :: 199712

DATA ITEMS CITED :: 35

MOLECULAR FORMULA :: C13-H5-N3-O7

MOLECULAR WEIGHT :: 315.21

WISWESSER LINE NOTATION :: L B656 HVJ CNW ENW KNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 9910 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >3500 mg/m3/6H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5026 mg/kg/14D-C

TOXIC EFFECTS :: Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 22295 mg/kg/13W-C

TOXIC EFFECTS :: Blood - changes in erythrocyte (RBC) count Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases Related to Chronic Data - changes in testicular weight

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 319 gm/kg/13W-C

TOXIC EFFECTS :: Liver - changes in liver weight Endocrine - changes in thymus weight

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1000 mg/kg

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors

TYPE OF TEST :: Unscheduled DNA synthesis

MUTATION DATA

TYPE OF TEST :: Mutation in mammalian somatic cells

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 1 ug/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 240,73,1990 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-GERMANY;Carcinogen JAN 1993

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2,4,7-三硝基-9-芴酮安全信息

[ 风险声明 (欧洲) ]:
R23/24/25

[ 安全声明 (欧洲) ]:
9-16-36/37/39

[ 危险品运输编码 ]:
387

[ 包装等级 ]:
II

[ 危险类别 ]:
1.1

[ 海关编码 ]:
2914700090

2,4,7-三硝基-9-芴酮合成路线

2,4,7-三硝基-9-芴酮海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%