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氯(2-二环己基膦基-2 ,4 ,6 -三异丙基-1,1 -联苯基)[2-(2 -氨基-1,1 -联苯)]钯(II)

名称

[ CAS 号 ]:
1310584-14-5

[ 中文名 ]:
氯(2-二环己基膦基-2',4',6'-三异丙基-1,1'-联苯基)[2-(2'-氨基-1,1'-联苯)]钯(II)

[ 英文名 ]:
chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II)

[英文别名 ]:

XPhos Pd G2

物理化学性质

[ 熔点 ]:
202-210 °C

[ 分子式 ]:
C₄₅H₅₇ClNPPd

[ 分子量 ]:
784.78800

[ 精确质量 ]:
783.29500

[ PSA ]:
13.59000

[ LogP ]:
14.05890

[ 储存条件 ]:
室温

MSDS

详细MSDS(安全技术说明书)

安全信息

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
36/37/38

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3.0

文献

Palladium-catalyzed α-arylation of 2-chloroacetates and 2-chloroacetamides.

J. Org. Chem. 78(8) , 4123-31, (2013)

A method has been developed for the Pd-catalyzed synthesis of α-(hetero)aryl esters and amides through a Suzuki-Miyaura cross-coupling reaction. This method avoids the use of strong base, does not nec...

Pd-catalyzed Suzuki-Miyaura cross-coupling reactions between sulfamates and potassium Boc-protected aminomethyltrifluoroborates.

Org. Lett. 15(10) , 2534-7, (2013)

Sulfamates were studied as the electrophilic partners in the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with potassium Boc-protected primary and secondary aminomethyltrifluoroborates. ...

Potassium Boc-protected secondary aminomethyltrifluoroborates: synthesis and Suzuki-Miyaura cross-coupling reactions.

Org. Lett. 14(17) , 4458-61, (2012)

Seven potassium Boc-protected secondary aminomethyltrifluoroborates were prepared in a standardized two-step process. The Suzuki-Miyaura cross-coupling reaction was studied with this new class of nucl...

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氯(2-二环己基膦基-2 ,4 ,6 -三异丙基-1,1 -联苯基)[2-(2 -氨基-1,1 -联苯)]钯(II)

名称

物理化学性质

MSDS

详细MSDS(安全技术说明书)

安全信息

文献

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