氧化钽
氧化钽用途
供拉钽酸锂单晶和制造高折射低色散特种光学玻璃用,化工中可作催化剂。
【用途二】
用于生产钽酸锂晶体和特种光学玻璃添加剂。
氧化钽名称
[ CAS 号 ]:
1314-61-0
[ 中文名 ]:
氧化钽
[ 英文名 ]:
Tantalum(V)oxide
[中文别名 ]:
[英文别名 ]:
- Tantalum(V)oxide
- Tantalum pentoxide
- MFCD00011254
- Tantalum(V) Oxide
- EINECS 215-238-2
- dioxotantaliooxy(dioxo)tantalum
氧化钽物理化学性质
[ 密度 ]:
8.2 g/mL at 25 °C(lit.)
[ 熔点 ]:
1872 °C
[ 分子式 ]:
O5Ta2
[ 分子量 ]:
441.89300
[ 精确质量 ]:
441.87100
[ PSA ]:
77.51000
[ 外观性状 ]:
白色至白色-米色粉末
[ 储存条件 ]:
置于密闭容器内,避免产生粉尘
氧化钽MSDS
氧化钽毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- WW5855000
- CHEMICAL NAME :
- Tantalum oxide
- CAS REGISTRY NUMBER :
- 1314-61-0
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 12
- MOLECULAR FORMULA :
- O5-Ta2
- MOLECULAR WEIGHT :
- 441.90
- WISWESSER LINE NOTATION :
- TA2 O5
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 8 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- EQSSDX Environmental Quality and Safety, Supplement. (Stuttgart, Fed. Rep. Ger.) V.1-5, 1975-76. Discontinued. Volume(issue)/page/year: 1,1,1975
- TYPE OF TEST :
- LD - Lethal dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Vascular - regional or general arteriolar or venous dilation Liver - other changes Blood - other changes
- REFERENCE :
- INMEAF Industrial Medicine. (Chicago, IL) V.1-18, 1932-49. For publisher information, see IOHSA5. Volume(issue)/page/year: 15,482,1946
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- >4 gm/kg
- TOXIC EFFECTS :
- Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - acute pulmonary edema Liver - hepatitis (hepatocellular necrosis), diffuse
- REFERENCE :
- HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 32(10-12),343,1967 *** REVIEWS *** ACGIH TLV-TWA 5 mg(Ta)/m3, dust DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 5mg(Ta)/m3, dust DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 5 mg/m3, dust CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 5 mg/m3, dust CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 5 mg/m3, dust CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-DENMARK:TWA 5 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
氧化钽安全信息
[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ 危害码 (欧洲) ]:
Xi
[ 风险声明 (欧洲) ]:
R36/37/38
[ 安全声明 (欧洲) ]:
S37/39-S26
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
-
[ RTECS号 ]:
WW5855000
氧化钽制备
1.氟钽酸钾法将氟钽酸钾与硫酸加热至400℃,反应物加水至沸,经充分稀释使酸化溶液水解,生成水合氧化物沉淀,再经分离、洗涤、烘干,得五氧化二钽成品。其
2.金属钽氧化法将金属钽片溶于硝酸、氢氟酸混酸中,经萃取提纯,用氨水沉淀氢氧化钽,再经水洗、烘干、灼烧、磨细,得五氧化二钽成品。其
3.钽酸加热脱水,或七氟合钽酸钾K2TaF7用浓硫酸灼烧分解,将其生成物用水抽提就可得到Ta2O5。纯五氧化二钽是将金属钽片或钽丝在氧气流中灼烧而成。
氧化钽文献
Appl. Opt. 24(4) , 490-495, (1985)
Intermixing at the tantalum oxide/silicon interface in gate dielectric structures. Alers GB, et al.
Appl. Phys. Lett. 73(11) , 1517-1519, (1998)
Synthesis and characterization of hexagonally packed mesoporous tantalum oxide molecular sieves. Antonelli DM and Ying JY
Chem. Mater. 8(4) , 874-881, (1996)
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产品详情:[Perfemiker]氧化钽(V),99.99% metals basis,用于光学玻璃或单晶
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