磷化锌

磷化锌用途

1.磷化锌可以毒杀各种鼠类，是一种优良的杀鼠剂。也可用作粮食仓库熏蒸剂。

2.高毒、急性无机杀鼠剂。鼠吞食后即与胃液中的盐酸作用，放出剧毒的磷化氢，使鼠类中枢神经系统麻痹，血压下降，休克致死。用于杀灭家鼠、田鼠及其他啮齿类动物。应用时一般配成毒饵，连续投药，鼠会产生拒食现象，可与其他杀鼠剂配合使用。
3.磷化锌还可用于树木保护，其原理是磷化锌遇酸释放出剧毒的磷化氢气体，将蛀干类害虫杀灭。目前使用的是熏蒸毒签。制作方法：将阿拉伯胶加水，加热溶解后加入定量的磷化锌，混均后用竹签一端蘸之。晾干后再蘸以草酸、阿拉伯胶，制成毒签。应用时插入有活虫的树洞中，深度3～9cm。也可按磷化锌：草酸为1:3(或1：4）混合后直接装入医用胶囊，使用时将胶囊堵住蛀干害虫损蚀过的洞口即可，防治效果96%。

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磷化锌名称

[ CAS 号 ]:
1314-84-7

[ 中文名 ]:
磷化锌

[ 英文名 ]:
zinc phosphide

[中文别名 ]:

耗鼠尽

[英文别名 ]:

Kilrat
delusal
blue-ox
trizinc diphosphide
EINECS 215-244-5
ZINC PHOSPHIDE
ratol
Delsal
MFCD00049631
rumetan

磷化锌物理化学性质

[ 密度 ]:
4,55 g/cm3

[ 沸点 ]:
1100°C

[ 熔点 ]:
420°C

[ 分子式 ]:
H₂P₂Zn₃

[ 分子量 ]:
260.10300

[ 闪点 ]:
1100°C

[ 精确质量 ]:
255.75100

[ PSA ]:
46.94000

[ LogP ]:
1.17950

[ 外观性状 ]:
灰色/黑色杂色颗粒

[ 储存条件 ]:
库房通风低温干燥,与碱、酸类、食品添加剂分开存放

磷化锌MSDS

详细MSDS(安全技术说明书)

磷化锌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: ZH4900000

CHEMICAL NAME :: Zinc phosphide

CAS REGISTRY NUMBER :: 1314-84-7

LAST UPDATED :: 199701

DATA ITEMS CITED :: 22

MOLECULAR FORMULA :: P2-Zn3

MOLECULAR WEIGHT :: 258.05

WISWESSER LINE NOTATION :: ZN3 P2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Human - woman

DOSE/DURATION :: 80 mg/kg

TOXIC EFFECTS :: Gastrointestinal - nausea or vomiting

REFERENCE :: ZACCAL Zacchia. Archivio di Medicina Legale, Sociale e Criminologica. Zacchia. Archives of Forensic, Social and Criminological Medicine. (Viale Regina Elena 336, Rome 00161, Italy) V.1-13, 1921-34; V.1- 1937- Volume(issue)/page/year: 23,144,1948

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Human - man

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AJPEAG American Journal of Public Health and the Nation's Health. (New York, NY) V.18-60, 1928-70. For publisher information, see AJHEAA. Volume(issue)/page/year: 36,1427,1946

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 12 mg/kg

TOXIC EFFECTS :: Gastrointestinal - other changes

REFERENCE :: MAGJAL Malaysian Agricultural Journal. (Ministry of Agriculture, Kuala Lumpur, Malaysia) V.45- 1965- Volume(issue)/page/year: 52(2),166,1979

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 450 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 31(9),24,1987

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 45 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 30,397,1979

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression

REFERENCE :: YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 31,1247,1980

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 263 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 31(9),24,1987

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 27,189,1976

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 28,329,1977

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - respiratory depression Lungs, Thorax, or Respiration - respiratory stimulation

REFERENCE :: JAPMA8 Journal of the American Pharmaceutical Association, Scientific Edition. (Washington, DC) V.29-49, 1940-60. For publisher information, see JPMSAE. Volume(issue)/page/year: 41,468,1952

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A421,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 13500 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A421,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - duck

DOSE/DURATION :: 37500 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A421,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - domestic

DOSE/DURATION :: 60 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,865,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - wild bird species

DOSE/DURATION :: 23700 ug/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,355,1983 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 910 mg/kg/13W-C

TOXIC EFFECTS :: Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death

REFERENCE :: IJEBA6 Indian Journal of Experimental Biology. (Publications & Information Directorate, CSIR, Hillside Rd., New Delhi 110 012, India) V.1- 1963- Volume(issue)/page/year: 18,854,1980

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1 mg/m3/17W-I

TOXIC EFFECTS :: Cardiac - pulse rate increase, without fall in BP Blood - pigmented or nucleated red blood cells Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 31(9),24,1987 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:TWA 0.1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2920 No. of Facilities: 275 (estimated) No. of Industries: 3 No. of Occupations: 3 No. of Employees: 3862 (estimated) No. of Female Employees: 48 (estimated)

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磷化锌安全信息

[ 危害码 (欧洲) ]:
F,T+,N

[ 风险声明 (欧洲) ]:
R15/29

[ 安全声明 (欧洲) ]:
S3/9/14-S30-S36/37-S45-S60-S61

[ 危险品运输编码 ]:
1714

[ RTECS号 ]:
ZH4900000

[ 包装等级 ]:
I

[ 危险类别 ]:
4.3

[ 海关编码 ]:
2848000010

磷化锌制备

1.合成法将赤磷和锌粉混合后，经高温烧成反应，然后冷却、粉碎，制得磷化锌成品。其

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磷化锌海关

[ 海关编码 ]: 2848000010

磷化锌

磷化锌用途

磷化锌名称

磷化锌物理化学性质

磷化锌MSDS

详细MSDS(安全技术说明书)

磷化锌毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

磷化锌安全信息

磷化锌制备

磷化锌海关

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