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N-氟代双苯磺酰胺

N-氟代双苯磺酰胺用途

【用途一】
主要作为氟化剂，比如为烯醇化合物提供F+
【用途二】
N-氟代双苯磺酰胺
【133745-75-2】
可对富电子芳香化合物、烯醇硅醚、烯醇锂盐等进行单氟化反应。

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N-氟代双苯磺酰胺名称

[ CAS 号 ]:
133745-75-2

[ 中文名 ]:
N-氟代双苯磺酰胺

[ 英文名 ]:
N-fluorobenzenesulfonamide

[中文别名 ]:

[英文别名 ]:

WSR&NFSWR
Benzenesulfonamide, N-fluoro-N-(phenylsulfonyl)-
Fluorodi(phenylsulfonyl)amine
N-Fluoro-N-(phenylsulfonyl)benzenesulfonamide
N-(benzenesulfonyl)-N-fluorobenzenesulfonamide
N-Fluorobis(phenylsulfonyl)amine
NFSI
N-Fluorodi(benzenesulfonyl)amine
MFCD00144885
N-fluorobenzenesulfonamide

N-氟代双苯磺酰胺物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
471.4±28.0 °C at 760 mmHg

[ 熔点 ]:
114-116 °C

[ 分子式 ]:
C₁₂H₁₀FNO₄S₂

[ 分子量 ]:
315.341

[ 闪点 ]:
238.9±24.0 °C

[ 精确质量 ]:
315.003540

[ PSA ]:
88.28000

[ LogP ]:
2.65

[ 外观性状 ]:
白色晶体

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 折射率 ]:
1.600

[ 储存条件 ]:
室温

N-氟代双苯磺酰胺MSDS

N-氟代双苯磺酰胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
26-37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2935009090

N-氟代双苯磺酰胺合成路线

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N-氟代双苯磺酰胺上游产品

N-氟代双苯磺酰胺下游产品

N-氟代双苯磺酰胺海关

[ 海关编码 ]: 2935009090

[ 中文概述 ]:
2935009090 其他磺（酰）胺. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:35.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

N-氟代双苯磺酰胺文献

Enantioselective fluorination of tert-butoxycarbonyl lactones and lactams catalyzed by chiral Pd(II)-bisphosphine complexes.

J. Org. Chem. 72 , 246, (2007)

An efficient catalytic enantioselective fluorination of tert-butoxycarbonyl lactones and lactams is reported. Reactions of the lactone substrates proceeded smoothly in an alcoholic solvent with a cata...

Statistical limits to the identification of ion channel domains by sequence similarity.

J. Fluor. Chem. 127 , 755, (2006)

The study of ion channel function is constrained by the availability of structures for only a small number of channels. A commonly used bioinformatics technique is to assert, based on sequence similar...

Development of GSKDevelopment of GSK's reagent guides – embedding sustainability into reagent selections reagent guides – embedding sustainability into reagent selection. Adams JP, et al.

Green Chem. 15 , 1542-1549 , (2013)

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