吡菌磷
吡菌磷用途
吡菌磷名称
[ CAS 号 ]:
13457-18-6
[ 中文名 ]:
吡菌磷
[ 英文名 ]:
Afugan
[中文别名 ]:
[英文别名 ]:
- PYRAZOPHOS
- EINECS 236-656-1
- Curamil
- MFCD00055494
- Afugan
吡菌磷物理化学性质
[ 密度 ]:
1.4±0.1 g/cm3
[ 熔点 ]:
51℃
[ 分子式 ]:
C14H20N3O5PS
[ 分子量 ]:
373.365
[ 精确质量 ]:
373.086121
[ PSA ]:
126.08000
[ LogP ]:
3.01
[ 折射率 ]:
1.596
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
吡菌磷MSDS
吡菌磷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TF2035000
- CHEMICAL NAME :
- Phosphorothioic acid, O,O-diethyl ester, O-ester with (6-ethoxycarbonyl-5-methyl) pyrazolo(1,5-a)pyrimidin-2-ol
- CAS REGISTRY NUMBER :
- 13457-18-6
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 6
- MOLECULAR FORMULA :
- C14-H20-N3-O5-P-S
- MOLECULAR WEIGHT :
- 373.40
- WISWESSER LINE NOTATION :
- T56 ANN FNJ COPS&O2&O2 G1 HVO2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 218 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- KHZDAN Khigiena i Zdraveopazvane. Hygiene and Sanitation. (Hemus, Blvd. Russki 6, Sofia, Bulgaria) V.9- 1966- Volume(issue)/page/year: 23,538,1980
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,734,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 435 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year: 11,1266,1989
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - quail
- DOSE/DURATION :
- 118 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,734,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 184 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year: 11,1266,1989 *** REVIEWS *** TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 53,99,1974
吡菌磷安全信息
[ 符号 ]:
GHS06, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H301-H332-H410
[ 警示性声明 ]:
P273-P301 + P310-P501
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ 危害码 (欧洲) ]:
Xn: Harmful;N: Dangerous for the environment;
[ 风险声明 (欧洲) ]:
20/22-50/53
[ 安全声明 (欧洲) ]:
36/37-46-60-61
[ 危险品运输编码 ]:
UN 2783
[ RTECS号 ]:
TF2035000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1(b)
吡菌磷制备
2-羰基甲基-2-乙氧基丙烯酸乙酯与3-氨基吡唑酮-5反应制得O-6-乙氧羰基-5-甲基-2-羟基吡唑基［1.5a］并嘧啶。然后在缚酸剂碳酸钠存在下，于50℃与犗，O-二乙基硫代磷酰氯反应，合成吡菌磷。3-氨基吡啶酮-5的制备可由下式表示：
吡菌磷文献
Probl. Khig. 10 , 52-8, (1985)
The authors investigate the 12 month effect of the organophosphorus pesticide "Pyrazophos", in the myocardium status of albino male rats treated per os by 1/20, 1/100, and 1/200 LD50 of the preparatio...
Removal of pyrazophos from treated fabric using household laundering.Bull. Environ. Contam. Toxicol. 42(5) , 687-90, (1989)
Pesticide residues in artichokes: effect of different head shape.
J. Environ. Sci. Health B 31(6) , 1189-99, (1996)
Residues of three pesticides (dimethoate, parathion, and pyrazophos) in two artichoke cultivars, Masedu and Spinoso sardo, were investigated. The amount of pesticides in artichokes was greatly affecte...
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