甜菜宁

甜菜宁用途

【用途一】
适用于甜菜地防除阔叶杂草，如繁缕、藜、芥菜、野燕麦、野芝麻、野萝卜、荠菜、牛舌草、鼬瓣花、牛藤菊等
【用途二】
甜菜地的芽后除草剂，防除繁缕、白芥、藜等杂草，于2～4叶期施药，用量为5～15g有效成分/100m² 。
【用途三】
该品是甜菜地的芽后除草剂。
【用途四】
该品是甜菜地的芽后除草剂

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甜菜宁名称

[ CAS 号 ]:
13684-63-4

[ 中文名 ]:
甜菜宁

[ 英文名 ]:
3-((Methoxycarbonyl)amino)phenyl m-tolylcarbamate

[中文别名 ]:

[英文别名 ]:

Phenmedipham
3-((Methoxycarbonyl)amino)phenyl m-tolylcarbamate
EINECS 237-199-0
MFCD00055419
3-methoxycarbonylaminophenyl 3-methylcarbanilate
methyl 3-(3-methylcarbaniloyloxy)carbanilate

甜菜宁生物活性

[ 描述 ]:

Phenmedipham 是一种氨基甲酸酯类除草剂。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Tânia Vidal, et al. Reproductive and Developmental Toxicity of the Herbicide Betanal® Expert and Corresponding Active Ingredients to Daphnia SPP. Environ Sci Pollut Res Int. 2016 Jul;23(13):13276-87.

甜菜宁物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
510.3±60.0 °C at 760 mmHg

[ 熔点 ]:
140-144°C

[ 分子式 ]:
C₁₆H₁₆N₂O₄

[ 分子量 ]:
300.309

[ 闪点 ]:
262.4±32.9 °C

[ 精确质量 ]:
300.110992

[ PSA ]:
76.66000

[ LogP ]:
4.42

[ 外观性状 ]:
无色晶体或白色粉末

[ 蒸汽压 ]:
0.0±1.4 mmHg at 25°C

[ 折射率 ]:
1.569

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

[ 水溶解性 ]:
<0.1 g/100 mL at 21 ºC

甜菜宁MSDS

甜菜宁安全信息

[ 符号 ]:

GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H410

[ 警示性声明 ]:
P273-P501

[ 个人防护装备 ]:
Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R50/53

[ 安全声明 (欧洲) ]:
S60-S61

[ 危险品运输编码 ]:
UN 3077

[ RTECS号 ]:
FD9050000

[ 海关编码 ]:
2924299038

甜菜宁合成路线

甜菜宁上下游产品

甜菜宁上游产品

甜菜宁下游产品

甜菜宁制备

制备方法一

由氯甲酸甲酯与间氨基苯酚在乙腈溶剂中反应，先制成3-甲氧羰基氨基苯酚，再与间甲苯异氰酸酯反应合成甜菜宁。

制备方法二

将3-甲氧羰基氨基苯酚在二甲基苯胺存在下与光气反应，生成氯甲酸（3-甲氧羰基氨基苯）酯，再在碳酸钠存以下与间甲基苯胺缩合，制得甜菜宁

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甜菜宁海关

[ 海关编码 ]: 2924299038

[ 中文概述 ]:
2924299038 甜菜安、特丁草胺、乙氧苯草胺等〔包括甜菜宁、戊菌隆、酰草隆、乙草胺、乙霉威〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2924299038 2-chloro-n-(ethoxymethyl)-n-(2-ethyl-6-methylphenyl)acetamide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

甜菜宁文献

Mining biologically-active molecules for inhibitors of fatty acid amide hydrolase (FAAH): Identification of phenmedipham and amperozide as FAAH inhibitors

Bioorg. Med. Chem. Lett. 19 , 6793-6, (2009)

The screening of known medicinal agents against new biological targets has been shown to be a valuable approach for revealing new pharmacology of marketed compounds. Recently, carbamate, urea and keto...

The influence of lipophilicity and formulation on the distribution of pesticides in laboratory-scale sediment/water systems.

Pest Manag. Sci. 59(2) , 238-44, (2003)

Pesticide reaching surface waters will be sorbed by sediment. This sorption process and the influence of pesticide formulation have been examined at 10 degrees C in small-scale systems having 2-cm dep...

Purification and properties of an Arthrobacter oxydans P52 carbamate hydrolase specific for the herbicide phenmedipham and nucleotide sequence of the corresponding gene.

J. Bacteriol. 174(20) , 6600-7, (1992)

Arthrobacter oxydans P52 isolated from soil samples was found to degrade the phenylcarbamate herbicides phenmedipham and desmedipham cometabolically by hydrolyzing their central carbamate linkages. Th...

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甜菜宁