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2,5-二甲基-1,4-苯醌

2,5-二甲基-1,4-苯醌名称

[ CAS 号 ]:
137-18-8

[ 中文名 ]:
2,5-二甲基-对苯醌

[ 英文名 ]:
2,5-Dimethylquinone

[中文别名 ]:

对二甲基醌

[英文别名 ]:

2,5-dimethyl-p-benzoquinone
2,5-Dimethyl-1,4-benzoquinone
MFCD00041737
EINECS 205-283-6
p-Xyloquinone
2,5-Dimethylbenzoquinone
2,5-Dimethyl-p-quinone
2,5-Cyclohexadiene-1,4-dione, 2,5-dimethyl-
2,5-dimethylcyclohexa-2,5-diene-1,4-dione
2,5-Dimethylquinone

2,5-二甲基-1,4-苯醌物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
200.9±15.0 °C at 760 mmHg

[ 熔点 ]:
123-125ºC

[ 分子式 ]:
C₈H₈O₂

[ 分子量 ]:
136.148

[ 闪点 ]:
71.1±17.4 °C

[ 精确质量 ]:
136.052429

[ PSA ]:
34.14000

[ LogP ]:
1.45

[ 外观性状 ]:
Crystalline Powder | Yellow to brown

[ 蒸汽压 ]:
0.3±0.4 mmHg at 25°C

[ 折射率 ]:
1.511

[ 储存条件 ]:
室温，干燥

[ 水溶解性 ]:
toluene: soluble0.5g/10 mL, clear to faintly turbid, yellow to brown

2,5-二甲基-1,4-苯醌MSDS

2,5-二甲基-1,4-苯醌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DK4800000

CHEMICAL NAME :: p-Benzoquinone, 2,5-dimethyl-

CAS REGISTRY NUMBER :: 137-18-8

LAST UPDATED :: 199701

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C8-H8-O2

MOLECULAR WEIGHT :: 136.16

WISWESSER LINE NOTATION :: L6V DVJ B1 E1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 290 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 11 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 43 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 40 nmol/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 347,37,1995

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2,5-二甲基-1,4-苯醌安全信息

[ 符号 ]:

GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H315-H319-H335

[ 警示性声明 ]:
P261-P301 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xn: Harmful;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
26-37/39

[ 危险品运输编码 ]:
UN 2811 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
DK4800000

[ 海关编码 ]:
2914690090

2,5-二甲基-1,4-苯醌合成路线

2,5-二甲基-1,4-苯醌上下游产品

2,5-二甲基-1,4-苯醌上游产品

2,5-二甲基-1,4-苯醌下游产品

2,5-二甲基-1,4-苯醌海关

[ 海关编码 ]: 2914690090

[ 中文概述 ]:
2914690090 其他醌. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ Summary ]:
2914690090 other quinones。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

2,5-二甲基-1,4-苯醌文献

Enantioselective total synthesis of cyathin A3.

Org. Lett. 9(15) , 2843-6, (2007)

The total synthesis of (-)-cyathin A3 is described. The key step involves an unusual enantioselective Diels-Alder reaction of 2,5-dimethyl-1,4-benzoquinone with 2,4-bis(trimethylsilyloxy)-1,3-pentadie...

Chemical defense of an opilionid (Acanthopachylus aculeatus).

J. Exp. Biol. 207(Pt 8) , 1313-21, (2004)

The opilionid Acanthopachylus aculeatus was shown to produce a defensive secretion containing quinones (2,3-dimethyl-1,4-benzoquinone, 2,5-dimethyl-1,4-benzoquinone and 2,3,5-trimethyl-1,4-benzoquinon...

Inhibition of jack bean urease by 1,4-benzoquinone and 2,5-dimethyl-1,4-benzoquinone. Evaluation of the inhibition mechanism.

J. Enzyme Inhib. Med. Chem. 17(4) , 247-53, (2002)

1,4-benzoquinone (BQ) and 2,5-dimethyl-1,4-benzoquinone (DMBQ) were studied as inhibitors of jack bean urease in 50 mM phosphate buffer, pH 7.0. The mechanisms of inhibition were evaluated by progress...

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