次氯酸锂

次氯酸锂用途

主要用作消毒剂和漂白剂
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次氯酸锂名称

[ CAS 号 ]:
13840-33-0

[ 中文名 ]:
次氯酸锂

[ 英文名 ]:
lithium,hypochlorite

[英文别名 ]:

次氯酸锂物理化学性质

[ 熔点 ]:
100ºC (Decomposes)

[ 分子式 ]:
ClLiO

[ 分子量 ]:
58.39340

[ 精确质量 ]:
57.97980

[ PSA ]:
23.06000

[ LogP ]:
0.57070

[ 外观性状 ]:
白色粉末带有一种微弱氯气味

次氯酸锂MSDS

次氯酸锂毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NH3486000
CHEMICAL NAME :
Hypochlorous acid, lithium salt
CAS REGISTRY NUMBER :
13840-33-0
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
Cl-O.Li
MOLECULAR WEIGHT :
58.39

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
5 gm/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 9(3),367,1990 *** REVIEWS *** IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 52,159,1991 IARC Cancer Review:Human No Available Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 52,159,1991 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 52,159,1991 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84133 No. of Facilities: 44 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 87 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84133 No. of Facilities: 1712 (estimated) No. of Industries: 4 No. of Occupations: 7 No. of Employees: 15810 (estimated) No. of Female Employees: 8533 (estimated)
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次氯酸锂安全信息

[ 危害码 (欧洲) ]:
O;C

[ 风险声明 (欧洲) ]:
R8

[ 安全声明 (欧洲) ]:
S17;S26;S45

[ 危险品运输编码 ]:
UN 1471

[ RTECS号 ]:
NH3486000

[ 包装等级 ]:
II

[ 危险类别 ]:
5.1

次氯酸锂合成路线

次氯酸锂上下游产品

次氯酸锂制备

制法 使LiOH在饱和LiOH水溶液中悬浮,通入氯气氯化。副产物LiCl在最初结晶时除去。分离得一水次氯酸锂。用叔丁醇洗涤纯化。然后在减压下稍微加热脱水。为减少LiCl的生成,反应常常在NaOH或KOH存在下进行。

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