乙酰丙酮锰(II)
乙酰丙酮锰(II)用途
乙酰丙酮锰(II)名称
[ CAS 号 ]:
14024-58-9
[ 中文名 ]:
双(2,4-戊二酮)锰(II)二水合物
[ 英文名 ]:
2,4-Pentanedione-manganese (2:1)
[中文别名 ]:
[英文别名 ]:
- Acetylacetone Manganese(II) Salt
- Manganese(II) Acetylacetonate Dihydrate
- EINECS 237-858-2
- Manganese(II) Acetyllacetonate
- 2,4-Pentanedione manganese(II) derivative
- 2,4-Pentanedione, manganese salt (2:1)
- Manganese(II) acetylacetonate
- Manganese(II) bis(acetylacetonate)
- Acetylacetone Manganese(II) Salt Dihydrate
- MFCD00000022
乙酰丙酮锰(II)物理化学性质
[ 密度 ]:
1.6 g/cm3
[ 沸点 ]:
138.4ºC at 760 mmHg
[ 熔点 ]:
180ºC
[ 分子式 ]:
C10H16MnO4
[ 分子量 ]:
255.170
[ 闪点 ]:
43.1ºC
[ 精确质量 ]:
255.042908
[ PSA ]:
68.28000
[ LogP ]:
1.10900
[ 外观性状 ]:
黄褐色或淡棕色结晶粉末
[ 蒸汽压 ]:
0.174mmHg at 25°C
[ 储存条件 ]:
库房低温,通风,干燥
[ 稳定性 ]:
hygroscopic
[ 水溶解性 ]:
11.5g/l | Soluble in water
乙酰丙酮锰(II)MSDS
乙酰丙酮锰(II)毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- OO9350000
- CHEMICAL NAME :
- Manganese, bis(2,4-pentanedionato-O,O')-
- CAS REGISTRY NUMBER :
- 14024-58-9
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 21
- MOLECULAR FORMULA :
- C10-H14-Mn-O4
- MOLECULAR WEIGHT :
- 253.18
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1200 mg/kg/26W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Tumorigenic - tumors at site of application
- REFERENCE :
- JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 60,1171,1978
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1350 mg/kg/21W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Musculoskeletal - tumors Tumorigenic - tumors at site of application
- REFERENCE :
- NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. (San Francisco, CA 94117) Volume(issue)/page/year: PH43-64-886 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 5 mg(Mn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,149,1971 OSHA PEL (Gen Indu):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 5 mg(Mn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
乙酰丙酮锰(II)安全信息
[ 符号 ]:
GHS07, GHS08
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302 + H312 + H332-H315-H319-H335-H351
[ 警示性声明 ]:
P261-P280-P305 + P351 + P338
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn: Harmful;
[ 风险声明 (欧洲) ]:
R20/21/22
[ 安全声明 (欧洲) ]:
S26;S36
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
3
[ RTECS号 ]:
OO9350000
乙酰丙酮锰(II)上下游产品
乙酰丙酮锰(II)上游产品
乙酰丙酮锰(II)下游产品
乙酰丙酮锰(II)制备
无水乙酰丙酮锰(Ⅱ)通常是将二水合物在100℃加热1h除去结晶水后得到的。
二水乙酰丙酮锰(Ⅱ)是由下面的反应制得的。将含有20g(0.2mol)乙酰丙酮的1mol/L NaOH溶液200mL加入到溶有20g(0.1mol)四水合二氯化锰的100mL水溶液中。所得到的固体产物在200mL 50%的乙醇水溶液中进行重结晶。晶体在二氧化碳气体保护下,在放有浓硫酸的干燥器中干燥。生成25g粗产物,收率87%。重结晶后得到15g黄色针状晶体,收率52%。乙酰丙酮锰(II)文献
Nanotechnology 25(27) , 275102, (2014)
In this study, we developed the maleimidyl magnetic nanoplatform, which enables functional targeting of a biomarker-specific moiety for molecular imaging via MRI. The maleimide group of the maleimidyl...
Local vanadium release from a calcium sulfate carrier accelerates fracture healing.J. Orthop. Res. 32(5) , 727-34, (2014)
This study evaluated the efficacy of using calcium sulfate (CaSO4 ) as a carrier for intramedullary delivery of an organic vanadium salt, vanadyl acetylacetonate (VAC) after femoral fracture. VAC can ...
Size- and shape-dependent peroxidase-like catalytic activity of MnFe2O4 Nanoparticles and their applications in highly efficient colorimetric detection of target cancer cells.Dalton Trans. 44 , 12871-7, (2015)
The catalytic activity of nanocrystal catalysts depends strongly on their chemical composition, size, and shape. Herein, we report four different sizes and shapes of MnFe2O4 nanoparticles (NPs) prepar...
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产品详情:双(乙酰丙酮)锰(II)
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¥158.0/25g
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产品详情:乙酰丙酮锰(II)
公司名:上海阿拉丁生化科技股份有限公司
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¥29.9/5g
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联系人:阿拉丁
产品详情:双(2,4-戊二酮)锰 二水合物
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区域:上海市嘉定区
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¥44.0/5g
¥118.0/25g
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¥1187.0/500g
联系人:夏言
产品详情:[Perfemiker]乙酰丙酮锰(II),≥97%
公司名:中山市迪欣化工有限公司
区域:中山市三角镇
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¥90.0/100kg
联系人:王洁
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