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(S)-3,3'-二苯基-[2,2'-联二萘]-1,1'-二醇

名称

[ CAS 号 ]:
147702-14-5

[ 中文名 ]:
(2S)-(-)-3,3′-二苯基-[2,2′-双萘]-1,1′-二醇

[ 英文名 ]:
(2S)-3,3'-Diphenyl[2,2'-binaphthalene]-1,1'-diol

[英文别名 ]:

MFCD08459338
3,3'-Diphenyl-2,2'-binaphthalene-1,1'-diol
[2,2'-Binaphthalene]-1,1'-diol, 3,3'-diphenyl-

物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
580.1±50.0 °C at 760 mmHg

[ 熔点 ]:
199-203°C

[ 分子式 ]:
C₃₂H₂₂O₂

[ 分子量 ]:
438.516

[ 闪点 ]:
251.7±24.7 °C

[ 精确质量 ]:
438.161987

[ LogP ]:
6.94

[ 蒸汽压 ]:
0.0±1.7 mmHg at 25°C

[ 折射率 ]:
1.727

[ 储存条件 ]:
2-8°C

安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H315-H318-H335-H413

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R41;R37/38

[ 安全声明 (欧洲) ]:
S26;S36/S37/S39

[ 危险品运输编码 ]:
NONH for all modes of transport

文献

New synthesis of vaulted biaryl ligands via the Snieckus phenol synthesis.

Org. Lett. 7 , 367, (2005)

[reaction: see text] In an effort to develop a synthesis of the VAPOL ligand that avoids the use of a chromium carbene complex, a route was examined that involved the annulation of a naphthalene carbo...

Highly enantioselective deracemization of linear and vaulted biaryl ligands.

Org. Lett. 5 , 1813, (2003)

[reaction: see text] A copper-mediated deracemization of the vaulted biaryl ligands VANOL and VAPOL can be readily achieved in the presence of (-)-spartiene. The optimal procedure involves the in situ...

Bao. J. et al.

J. Am. Chem. Soc. 118 , 3392, (1996)

更多文献

(S)-3,3'-二苯基-[2,2'-联二萘]-1,1'-二醇

名称

物理化学性质

安全信息

文献

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