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四氯合铜酸二锂

四氯合铜酸二锂用途

用于格氏试剂与溴代烷或甲苯磺酸醋的交叉偶合反应。

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四氯合铜酸二锂名称

[ CAS 号 ]:
15489-27-7

[ 中文名 ]:
四氯合铜酸二锂

[ 英文名 ]:
lithium tetrachlorocuprate

[中文别名 ]:

[英文别名 ]:

MFCD00011081
Dilithium Tetrachlorocuprate(II)
Lithium tetrachlorocuprate
Dilithium Tetrachlorocopper(II)
EINECS 203-726-8

四氯合铜酸二锂物理化学性质

[ 密度 ]:
0.91 g/mL at 25ºC

[ 沸点 ]:
66ºC

[ 分子式 ]:
Cl₄CuLi₂

[ 分子量 ]:
219.24000

[ 闪点 ]:
1 °F

[ 精确质量 ]:
216.83700

[ LogP ]:
2.75550

[ 外观性状 ]:
Liquid | Dark orange

[ 储存条件 ]:
Flammables area

[ 水溶解性 ]:
Difficult to mix.

四氯合铜酸二锂MSDS

详细MSDS(安全技术说明书)

四氯合铜酸二锂安全信息

[ 符号 ]:

GHS02, GHS07, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302-H319-H335-H351

[ 补充危害声明 ]:
May form explosive peroxides.

[ 警示性声明 ]:
P210-P280-P301 + P312 + P330-P305 + P351 + P338-P370 + P378-P403 + P235

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F,Xi

[ 风险声明 (欧洲) ]:
R11

[ 安全声明 (欧洲) ]:
S16

[ 危险品运输编码 ]:
UN 1993 3

[ WGK德国 ]:
1

[ 包装等级 ]:
II

[ 危险类别 ]:
3.0

[ 海关编码 ]:
28429090

四氯合铜酸二锂制备

将0.2摩尔氯化锂和0.1摩尔氯化铜在1000毫升四氢呋喃中反应，制得四氯铜酸二钾的四氢呋喃溶液。

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四氯合铜酸二锂文献

Regioselective halogenation of some 2,3-anhydro pyrimidine nucleosides with dilithium tetrahalocuprates.

Nucleic Acids Symp. Ser. (27) , 109-10, (1992)

The reaction of 1-(2,3-anhydro-5-O-trityl-beta-D-lyxofuranosyl)-2-O-methyluracil (1a) and its thymine analogue (1b) with dilithium tetrahalocuprate (Li2CuX4) revealed excellent to perfect regioselecti...

New syntheses of 1,7-dimethylnonyl propanoate, the western corn rootworm pheromone, in four different ways via cross metathesis, alkylation and coupling reactions.

Biosci. Biotechnol. Biochem. 74(3) , 595-600, (2010)

A mixture of the four stereoisomers of 1,7-dimethylnonyl propanoate, the female sex pheromone of the western corn rootworm (Diabrotica virgifera virgifera LeConte), was synthesized in four different w...

Tetrahedron 62 , 4851, (2006)

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