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SnAP DA试剂

SnAP DA试剂名称

[ CAS 号 ]:
1577233-73-8

[ 中文名 ]:
SnAP DA试剂

[ 英文名 ]:
SnAP DA Reagent

[英文别名 ]:

MFCD29037001
SnAP DA Reagent
S167607

SnAP DA试剂物理化学性质

[ 沸点 ]:
472.3±55.0 °C at 760 mmHg

[ 分子式 ]:
C₂₁H₄₆N₂O₂Sn

[ 分子量 ]:
477.31

[ 闪点 ]:
239.4±31.5 °C

[ 精确质量 ]:
478.258118

[ LogP ]:
9.44

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 储存条件 ]:
2-8°C

SnAP DA试剂安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311 + H331-H315-H319-H335-H410

[ 警示性声明 ]:
P261-P273-P280-P301 + P310-P305 + P351 + P338-P311

[ 危害码 (欧洲) ]:
T

[ 危险品运输编码 ]:
UN 2788 6.1 / PGIII

SnAP DA试剂文献

SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.

Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)

SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.

Nature Chemistry 6(4) , 310-4, (2014)

Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially ...

One-step synthesis of saturated spirocyclic N-heterocycles with stannyl amine protocol (SnAP) reagents and ketones.

J. Am. Chem. Soc. 136(51) , 17726-9, (2014)

The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions. The resulting, N-unprotected ...

更多文献

SnAP DA试剂

SnAP DA试剂名称

SnAP DA试剂物理化学性质

SnAP DA试剂安全信息

SnAP DA试剂文献

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