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双(2,4-二硝基苯基)草酸酯

双(2,4-二硝基苯基)草酸酯名称

[ CAS 号 ]:
16536-30-4

[ 中文名 ]:
双(2,4-二硝基苯基)草酸酯

[ 英文名 ]:
BIS(2,4-DINITROPHENYL) OXALATE

[中文别名 ]:

[英文别名 ]:

MFCD00010712
2,4-Dinitrophenyl oxalate
Ethanedioic acid, bis(2,4-dinitrophenyl) ester
Oxalic acid bis(2,4-dinitrophenyl) ester
2,4-Dinitrophenyloxalat
BIS(2,4-DINITROPHENYL) OXALATE
bis(2,4-dinitrophenyl)oxalate
DNPO

双(2,4-二硝基苯基)草酸酯物理化学性质

[ 密度 ]:
1.8±0.1 g/cm3

[ 沸点 ]:
605.1±55.0 °C at 760 mmHg

[ 熔点 ]:
189-190 °C(lit.)

[ 分子式 ]:
C₁₄H₆N₄O₁₂

[ 分子量 ]:
422.217

[ 闪点 ]:
265.9±33.5 °C

[ 精确质量 ]:
421.998230

[ PSA ]:
235.88000

[ LogP ]:
3.51

[ 外观性状 ]:
淡黄色粉末

[ 蒸汽压 ]:
0.0±1.7 mmHg at 25°C

[ 折射率 ]:
1.674

[ 储存条件 ]:
−20°C

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents, strong bases.

双(2,4-二硝基苯基)草酸酯MSDS

双(2,4-二硝基苯基)草酸酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36

[ 危险品运输编码 ]:
1325.0

[ WGK德国 ]:
3

[ 危险类别 ]:
4.1

[ 海关编码 ]:
2917119000

双(2,4-二硝基苯基)草酸酯合成路线

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双(2,4-二硝基苯基)草酸酯海关

[ 海关编码 ]: 2917119000

[ 中文概述 ]:
2917119000 其他草酸盐和酯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 对苯二甲酸请注明4-CBA值, 对苯二甲酸请注明P-TL酸值, 对苯二甲酸请注明色度, 对苯二甲酸请注明水分

[ Summary ]:
2917119000 oxalic acid salts and esters VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

双(2,4-二硝基苯基)草酸酯文献

Determination of fluorophor-labeled compounds based on peroxyoxalate chemiluminescence.

Anal. Biochem. 136 , 277, (1984)

Fluorophor-labeled compounds are determined by adding an aromatic oxalate ester and hydrogen peroxide and measuring the resulting chemiluminescence (CL). Rhodamine B is excited more efficiently than 2...

Optimization of an HPLC peroxyoxalate chemiluminescence detection system for some dansyl amino acids.

J. Biolumin. Chemilumin. 5(1) , 13-23, (1990)

Bis(2,4,6-trichlorophenyl) oxalate (TCPO)-hydrogen-peroxide-generated chemiluminescence (CL) of four dansyl amino acids has been used as a model system for the optimization of a detection system in re...

Kinetics and Mechanism of the Nucleophilic Substitution Reaction of Imidazole with Bis(2,4,6-trichlorophenyl) Oxalate and Bis(2,4-dinitrophenyl) Oxalate.

J. Org. Chem. 61(8) , 2657-2663, (1996)

The kinetics of the imidazole-catalyzed decomposition of bis(2,4,6-trichlorophenyl) oxalate (TCPO) and bis(2,4-dinitrophenyl) oxalate (DNPO) was investigated by the stopped-flow technique. Pseudo-firs...

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