敌瘟磷
敌瘟磷用途
广谱性有机磷杀菌剂，有内吸作用，兼有保护和治疗作用。主要用于防治稻瘟病，对水稻叶瘟、穗颈瘟、苗瘟有良好防效。如防治叶瘟在病前40%用乳油7.5～10.5mL/100m2对水喷雾；重发时用11.3～15mL/100m2隔10～14d喷雾；同样剂量可防治穗颈瘟；种子处理可防治苗瘟。此外还可用于防治麦类赤霉病、水稻小粒菌核病、水稻纹枯病、玉米大斑病和小斑病、胡麻叶斑病及稻叶蝉、飞虱、稻螟等。本药剂在病原菌侵入前使用效果明显。
敌瘟磷名称
[ CAS 号 ]:
17109-49-8
[ 中文名 ]:
敌瘟磷
[ 英文名 ]:
edifenphos
[中文别名 ]:
[英文别名 ]:
- MFCD00078673
- O-ethyl S,S-diphenyl phosphorodithioate
- Edifenphos
- EINECS 241-178-1
- [ethoxy(phenylsulfanyl)phosphoryl]sulfanylbenzene
- EDDP
敌瘟磷物理化学性质
[ 密度 ]:
1.27 g/cm3
[ 沸点 ]:
430.2ºC at 760 mmHg
[ 分子式 ]:
C14H15O2PS2
[ 分子量 ]:
310.37100
[ 闪点 ]:
214ºC
[ 精确质量 ]:
310.02500
[ PSA ]:
86.71000
[ LogP ]:
5.71560
[ 外观性状 ]:
黄色至棕色液体带有一种特有的气味
[ 蒸汽压 ]:
3.32E-07mmHg at 25°C
[ 折射率 ]:
1.618
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
敌瘟磷MSDS
敌瘟磷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TE3850000
- CHEMICAL NAME :
- Phosphorodithioic acid, O-ethyl-S,S-diphenyl ester
- CAS REGISTRY NUMBER :
- 17109-49-8
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 17
- MOLECULAR FORMULA :
- C14-H15-O2-P-S2
- MOLECULAR WEIGHT :
- 310.38
- WISWESSER LINE NOTATION :
- 2OPO&SR&SR
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 650 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 615 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 26 mg/kg
- TOXIC EFFECTS :
- Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 212 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 143 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - chicken
- DOSE/DURATION :
- 550 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - domestic
- DOSE/DURATION :
- 45 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Gastrointestinal - hypermotility, diarrhea
- TYPE OF TEST :
- Cytogenetic analysis
- TYPE OF TEST :
- Micronucleus test
- TYPE OF TEST :
- Cytogenetic analysis
- TYPE OF TEST :
- Cytogenetic analysis
MUTATION DATA
- TEST SYSTEM :
- Rodent - mouse
- DOSE/DURATION :
- 26500 ug/kg
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 322,77,1994 *** REVIEWS *** TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 53,99,1974
敌瘟磷安全信息
[ 符号 ]:
GHS06, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H301 + H311 + H331-H317-H410
[ 警示性声明 ]:
P261-P273-P280-P301 + P310-P311-P501
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
T: Toxic;N: Dangerous for the environment;
[ 风险声明 (欧洲) ]:
R21;R23/25;R43;R50/53
[ 安全声明 (欧洲) ]:
S36/37-S45-S60-S61
[ 危险品运输编码 ]:
UN 2810
[ RTECS号 ]:
TE3850000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1(b)
[ 海关编码 ]:
2930909058
敌瘟磷制备
1.乙基磷酰二氯的制备三氯氧磷与无水乙醇作用，无水乙醇稍过量，制得O-乙基磷酰二氯。
2.苯硫酚钠的制备苯氯磺化制得苯磺酰氯，然后在硫酸和锌粉（或铁粉）存在下转化成苯硫酚，中和得相应的酚钠。
3.敌瘟磷合成O-乙基磷酰二氯与苯硫酚钠作用，合成敌瘟磷。规格30%、50%磷乳油；25%、30%磷可湿性粉剂；1.5%、2%、敌瘟磷粉剂。
敌瘟磷海关
[ 海关编码 ]: 2930909058
[ 中文概述 ]:
2930909058 稻瘟净、异稻瘟净、稻丰散等〔包括敌瘟磷〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%
[ Summary ]:
2930909058 o-ethyl s,s-diphenyl phosphorodithioate
敌瘟磷文献
Eur. J. Med. Chem. 46 , 618-30, (2011)
A QSAR based predictive model of hERG activity in terms of 'global descriptors' has been developed and evaluated. The QSAR was developed by training 77 compounds covering a wide range of activities an...
Detection of iprobenfos and edifenphos using a new multi-aptasensor.Anal. Chim. Acta 868 , 60-6, (2015)
The sensitive detection of iprobenfos (IBF) and edifenphos (EDI) was successfully conducted by using a new aptamer-based colorimetric multi-aptasensor. The dissociation constants of this multi-target ...
The Neurospora crassa chs-2 gene encodes a non-essential chitin synthase.Microbiology 140 ( Pt 9) , 2189-97, (1994)
Chitin is a structural component of morphologically distinct structures assembled during various phases of growth and development in filamentous fungi. In Neurospora crassa, at least three different D...
推荐生产厂家/供应商：
公司名：上海化源世纪贸易有限公司
区域：上海市普陀区
价格：
联系人：徐经理
产品详情：敌瘟磷标准溶液
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥118.0/1ml
联系人：刘佳
产品详情：敌瘟磷标准溶液
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥需询单/1mg
￥需询单/1g
￥需询单/1g
￥需询单/1g
联系人：阿拉丁
产品详情：甲醇中敌瘟磷溶液
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相关化合物
【敌瘟磷】化源网提供敌瘟磷CAS号17109-49-8，敌瘟磷MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询敌瘟磷上化源网，专业又轻松。>>电脑版：敌瘟磷
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