杀虫磺
杀虫磺用途
用于防治水稻二化螟、三化螟、小菜蛾、马铃薯象甲、葡萄缀穗蛾等鳞翅目和鞘翅目害虫
【用途二】
该品具有胃毒、触杀作用，使害虫麻痹中毒拒食而死亡。可在马铃薯、玉米、水稻上防治多种害虫，对水稻螟虫、马铃薯甲虫、小菜蛾等鳞翅目和鞘翅目害虫有很强的杀灭作用。
杀虫磺名称
[ CAS 号 ]:
17606-31-4
[ 中文名 ]:
杀虫磺
[ 英文名 ]:
bensultap
[中文别名 ]:
[英文别名 ]:
- MFCD00210246
- Nereistoxin dibenzenesulfonate
- Bensultap
- ZZ-Doricida
- Ruban
- Bensultap [BSI:ISO]
- TI-78
- Victenon
- Bancol
- ZZ-Doricida Insecticide
杀虫磺物理化学性质
[ 密度 ]:
1.353g/cm3
[ 沸点 ]:
590.8ºC at 760mmHg
[ 熔点 ]:
82 - 83ºC
[ 分子式 ]:
C17H21NO4S4
[ 分子量 ]:
431.61300
[ 闪点 ]:
311.1ºC
[ 精确质量 ]:
431.03500
[ PSA ]:
138.88000
[ LogP ]:
5.32240
[ 蒸汽压 ]:
6.22E-14mmHg at 25°C
[ 折射率 ]:
1.62
[ 储存条件 ]:
0-6°C
杀虫磺毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- DB8000000
- CHEMICAL NAME :
- Benzenesulfonic acid, thio-, S,S'-(2-(dimethylamino)trimethylene) ester
- CAS REGISTRY NUMBER :
- 17606-31-4
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 18
- MOLECULAR FORMULA :
- C17-H21-N-O4-S4
- MOLECULAR WEIGHT :
- 431.63
- WISWESSER LINE NOTATION :
- WSR&S1YN1&1&1SSWR
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1105 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >700 mg/m3
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - ptosis Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 438 mg/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - ptosis Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1160 mg/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - ptosis Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 415 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 343 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1202 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - chicken
- DOSE/DURATION :
- 103 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - quail
- DOSE/DURATION :
- 60 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 5460 mg/kg/13W-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight Blood - pigmented or nucleated red blood cells
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 21840 mg/kg/2Y-C
- TOXIC EFFECTS :
- Cardiac - changes in heart weight Liver - multiple effects Liver - changes in liver weight
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 3276 mg/kg/13W-C
- TOXIC EFFECTS :
- Liver - other changes Blood - normocytic anemia Blood - changes in bone marrow (not otherwise specified)
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 43680 mg/kg/1Y-C
- TOXIC EFFECTS :
- Gastrointestinal - other changes Kidney, Ureter, Bladder - other changes Blood - changes in erythrocyte (RBC) count
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 87360 mg/kg/2Y-C
- TOXIC EFFECTS :
- Blood - pigmented or nucleated red blood cells Blood - other changes Blood - changes in leukocyte (WBC) count
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 18200 mg/kg/1Y-C
- TOXIC EFFECTS :
- Liver - changes in liver weight Blood - normocytic anemia Nutritional and Gross Metabolic - weight loss or decreased weight gain
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 660 mg/kg
- SEX/DURATION :
- female 7-17 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - musculoskeletal system
MUTATION DATA
- TYPE OF TEST :
- Sister chromatid exchange
- TEST SYSTEM :
- Human Lymphocyte
- DOSE/DURATION :
- 1 mg/L
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 241,109,1990
杀虫磺安全信息
[ 符号 ]:
GHS07, GHS09
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302-H410
[ 警示性声明 ]:
P273-P501
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn: Harmful;N: Dangerous for the environment;
[ 风险声明 (欧洲) ]:
R22
[ 安全声明 (欧洲) ]:
S60-S61
[ 危险品运输编码 ]:
UN3077 9/PG 3
[ RTECS号 ]:
DB8000000
[ 海关编码 ]:
2930909065
杀虫磺制备
2-N,N-二甲氨基-1,3-二氯丙烷与硫代苯磺酸钠在乙醇中回流反应而制得。
杀虫磺海关
[ 海关编码 ]: 2930909065
[ 中文概述 ]:
2930909065 硫线磷、氯甲硫磷、杀虫磺等〔包括砜吸磷、砜拌磷、异拌磷、三硫磷、芬硫磷〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ 监管条件 ]: S.进出口农药登记证明
[ Summary ]:
2930909065 s-(2-(isopropylthio)ethyl) o,o-dimethyl phosphorodithioate
杀虫磺文献
Zhonghua Yu Fang Yi Xue Za Zhi 21(3) , 149-51, (1987)
[Detection of bancol for the purpose of forensic chemical expertise].
Sud. Med. Ekspert. 53(6) , 39-41, (2010)
Optimal conditions for the extraction of bancol from the biological material with toluene are described. The possibility of its purification and separation from co-extracted compounds on a silicagel L...
[Detection of bensultap (bancol) derivatives and metabolites by chromatographic methods].Sud. Med. Ekspert. 52(5) , 30-5, (2009)
This paper is designed to describe methods for the detection of derivatives and metabolites of the insecticidic agent bancol (nereistoxin precursor) by chromatographic methods including thin layer chr...
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