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甲酸烯丙酯

甲酸烯丙酯用途

有机合成。

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甲酸烯丙酯名称

[ CAS 号 ]:
1838-59-1

[ 中文名 ]:
甲酸烯丙酯

[ 英文名 ]:
allyl formate

[中文别名 ]:

甲酸烯丙脂

[英文别名 ]:

2-Propenyl methanoate
Formic acid, 2-propen-1-yl ester
prop-2-en-1-yl formate
UN2336
2-allyl formate
3-formyloxy-propene
Allyl formate
Ameisensaeure-allylester
formic acid,2-propenyl ester
Formic acid, allyl ester (8CI)

甲酸烯丙酯物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
84.5±9.0 °C at 760 mmHg

[ 熔点 ]:
9-10 °C(lit.)

[ 分子式 ]:
C₄H₆O₂

[ 分子量 ]:
86.089

[ 闪点 ]:
6.5±9.3 °C

[ 精确质量 ]:
86.036781

[ PSA ]:
26.30000

[ LogP ]:
0.60

[ 蒸汽压 ]:
72.2±0.2 mmHg at 25°C

[ 折射率 ]:
1.392

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放,不宜久储,以防聚合

甲酸烯丙酯MSDS

详细MSDS(安全技术说明书)

甲酸烯丙酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: LQ9800000

CHEMICAL NAME :: Formic acid, 2-propenyl ester

CAS REGISTRY NUMBER :: 1838-59-1

BEILSTEIN REFERENCE NO. :: 1735668

LAST UPDATED :: 199701

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C4-H6-O2

MOLECULAR WEIGHT :: 86.10

WISWESSER LINE NOTATION :: VHO2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 124 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity)

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 980 mg/m3

TOXIC EFFECTS :: Behavioral - general anesthetic Behavioral - somnolence (general depressed activity)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),55,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 96 mg/kg

TOXIC EFFECTS :: Behavioral - general anesthetic Behavioral - somnolence (general depressed activity)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),55,1984

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 610 mg/m3

TOXIC EFFECTS :: Behavioral - general anesthetic Behavioral - somnolence (general depressed activity)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),55,1984 *** REVIEWS *** TOXICOLOGY REVIEW AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 20,517,1959

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甲酸烯丙酯安全信息

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38:Irritating to eyes, respiratory system and skin .

[ 安全声明 (欧洲) ]:
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37:Wear suitable protective clothing and gloves . S37/39:Wear suitable gloves and eye/face protection .

[ 危险品运输编码 ]:
2336

[ WGK德国 ]:
3

[ 包装等级 ]:
I

[ 危险类别 ]:
3.1

[ 海关编码 ]:
2915120000

甲酸烯丙酯合成路线

详细合成路线

甲酸烯丙酯海关

[ 海关编码 ]: 2915120000

[ 中文概述 ]:
2915120000 甲酸盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%