六氯丙烯

【用途一】
用于有机合成。

[ 密度 ]:
1.8±0.1 g/cm3

[ 沸点 ]:
209.5±0.0 °C at 760 mmHg

[ 熔点 ]:
-73°C

[ 分子式 ]:
C₃Cl₆

[ 分子量 ]:
248.750

[ 闪点 ]:
69.9±23.3 °C

[ 精确质量 ]:
245.813110

[ LogP ]:
6.08

[ 外观性状 ]:
无色液体

[ 蒸汽密度 ]:
8.3 (vs air)

[ 蒸汽压 ]:
0.3±0.4 mmHg at 25°C

[ 折射率 ]:
1.554

[ 储存条件 ]:
室温

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

UD0175000

CHEMICAL NAME :

Propene, hexachloro-

CAS REGISTRY NUMBER :

1888-71-7

BEILSTEIN REFERENCE NO. :

1766640

LAST UPDATED :

199710

DATA ITEMS CITED :

9

MOLECULAR FORMULA :

C3-Cl6

MOLECULAR WEIGHT :

248.73

WISWESSER LINE NOTATION :

GYGUYGXGGG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

425 ppm/30M

TOXIC EFFECTS :

Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea Liver - hepatitis (hepatocellular necrosis), diffuse

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

400 uL/kg

TOXIC EFFECTS :

Liver - hepatitis (hepatocellular necrosis), diffuse Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis)

TYPE OF TEST :

LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

300 ppm/30M

TOXIC EFFECTS :

Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :

LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

85 ppm/30M

TOXIC EFFECTS :

Behavioral - excitement Lungs, Thorax, or Respiration - dyspnea

MUTATION DATA

TYPE OF TEST :

Mutation in microorganisms

TEST SYSTEM :

Bacteria - Salmonella typhimurium

DOSE/DURATION :

15 umol/L

REFERENCE :

MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 170,1,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X6277 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1822 (estimated) No. of Female Employees: 272 (estimated)

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H332-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R23;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3382 6.1/PG 1

[ WGK德国 ]:
3

[ RTECS号 ]:
UD0175000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2903299090

详细合成路线

将1,1,1,2,2,3,3-七氯丙烷溶于乙醇，保持30-40℃，滴加乙醇钾溶液，然后加热回流1h。将反应物中乙醇蒸出回收，冷却后倾入水中分层，取有机层用水洗涤，干燥，减压蒸馏，收集98-100℃（2.67kPa）馏分，得六氯丙烯，收率86.7-89.2

[ 海关编码 ]: 2903299090

[ 中文概述 ]:
HS: 2903299090. 其他无环烃的不饱和氯化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Mutagenicity of chloroolefins in the Salmonella/mammalian microsome test. III. Metabolic activation of the allylic chloropropenes allyl chloride, 1,3-dichloropropene, 2,3-dichloro-1-propene, 1,2,3-trichloropropene, 1,1,2,3-tetrachloro-2-propene and hexachloropropene by S9 mix via two different metabolic pathways.

Mutat. Res. 170(1-2) , 1-9, (1986)

In the presence of S9 mix all allylic chloropropenes tested exert considerable indirect mutagenic activity which is most pronounced for 1,2,3-trichloropropene. Lower as well as higher chlorinated deri...

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公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：六氯丙烯

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥399.9/25g ￥784.9/100g ￥需询单/1g ￥需询单/25g

联系人：阿拉丁

产品详情：六氯丙烯

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公司名：上海创赛科技有限公司

区域：上海市嘉定区

价格：
￥562.0/50g ￥2257.0/250g ￥493.0/50g ￥1978.0/250g

联系人：夏言

产品详情：[Perfemiker]六氯丙烯,98%

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