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苄氧乙酰氯

苄氧乙酰氯用途

【用途一】
β-内酰胺的非对称合成试剂。

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苄氧乙酰氯名称

[ CAS 号 ]:
19810-31-2

[ 中文名 ]:
苄氧基乙酰氯

[ 英文名 ]:
2-(Benzyloxy)acetyl chloride

[中文别名 ]:

苄氧乙酰氯

[英文别名 ]:

2-(benzyloxy)ethanoyl chloride
2-(phenylmethoxy)acetyl chloride
Benzyloxyacetylchloride
benzyloxyacetic acid chloride
MFCD00010768
(Benzyloxy)acetyl chloride
2-(benzyloxy)acetyl chloride
ACETYL CHLORIDE,(PHENYLMETHOXY)
Benzyloxyacetyl Chloride
benzyloxyacetic chloride

苄氧乙酰氯物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
282.3±0.0 °C at 760 mmHg

[ 分子式 ]:
C₉H₉ClO₂

[ 分子量 ]:
184.620

[ 闪点 ]:
96.4±20.8 °C

[ 精确质量 ]:
184.029114

[ PSA ]:
26.30000

[ LogP ]:
2.51

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.525

[ 储存条件 ]:
−20°C

苄氧乙酰氯MSDS

苄氧乙酰氯安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 补充危害声明 ]:
Reacts violently with water.

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R14;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3265 8/PG 2

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2918990090

苄氧乙酰氯合成路线

苄氧乙酰氯上下游产品

苄氧乙酰氯上游产品

苄氧乙酰氯下游产品

苄氧乙酰氯海关

[ 海关编码 ]: 2918990090

[ 中文概述 ]:
2918990090. 其他含其他附加含氧基羧酸（包括酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

苄氧乙酰氯文献

Asymmetric synthesis of 1-(2- and 3-haloalkyl)azetidin-2-ones as precursors for novel piperazine, morpholine, and 1,4-diazepane annulated beta-lactams.

J. Org. Chem. 71 , 7083, (2006)

A high-yielding, asymmetric synthesis of novel 4-formyl-1-(2- and 3-haloalkyl)azetidin-2-ones was developed as valuable starting materials for the synthesis of different enantiomerically enriched bicy...

Stereoselective synthesis of (S)-3-(methylamino)-3-((R)-pyrrolidin-3-yl)propanenitrile.

J. Org. Chem. 77(10) , 4732-9, (2012)

(S)-3-(methylamino)-3-((R)-pyrrolidin-3-yl)propanenitrile (1) is a key intermediate in the preparation of PF-00951966, (1) a fluoroquinolone antibiotic for use against key pathogens causing community-...

J. Org. Chem. 59 , 932, (1994)

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