氢氧化铯 溶液
氢氧化铯 溶液名称
[ CAS 号 ]:
21351-79-1
[ 中文名 ]:
氢氧化铯
[ 英文名 ]:
Cesium hydroxide
[英文别名 ]:
- Cesium hydroxide
- MFCD00010964
- Caesium hydroxide
- EINECS 244-344-1
氢氧化铯 溶液物理化学性质
[ 密度 ]:
3.68 g/mL at 25 °C(lit.)
[ 沸点 ]:
100ºC at 760 mmHg
[ 熔点 ]:
272 °C(lit.)
[ 分子式 ]:
CsOH
[ 分子量 ]:
149.913
[ 精确质量 ]:
149.908188
[ PSA ]:
23.06000
[ 外观性状 ]:
无色液体/白色固体
[ 储存条件 ]:
库房通风低温干燥,与酸类分开存放
[ 稳定性 ]:
Stable. Incompatible with acids. Absorbs carbon dioxide from the air.
[ 水溶解性 ]:
soluble
氢氧化铯 溶液MSDS
氢氧化铯 溶液毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- FK9800000
- CHEMICAL NAME :
- Cesium hydroxide
- CAS REGISTRY NUMBER :
- 21351-79-1
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 20
- MOLECULAR FORMULA :
- Cs-H-O
- MOLECULAR WEIGHT :
- 149.92
- WISWESSER LINE NOTATION :
- CS Q
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 32,239,1975
- TYPE OF TEST :
- Rinsed with water
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 32,239,1975 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 570 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - other changes
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 21(1),29,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- AIHOAX Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.1-2(3), 1950. For publisher information, see AEHLAU. Volume(issue)/page/year: 1,637,1950
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 800 mg/kg
- TOXIC EFFECTS :
- Behavioral - tetany
- REFERENCE :
- 20PKA3 "Novye Dannye Po Toksikologii Redkikh Metalov Ikh Soedinenii," New Data on the Toxicology of Rare Metals and Their Compounds, Izrael'son, Z.I., ed., Moscow, Izdatel'stvo "Meditsina," 1967 Volume(issue)/page/year: -,-,1967 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 10110 ug/m3/17W-I
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 21(1),29,1977 *** REVIEWS *** ACGIH TLV-TWA 2 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg/m3 JAN 1993 OEL-DENMARK:TWA 2 mg/m3 JAN 1993 OEL-FINLAND:TWA 2 mg/m3 JAN 1993 OEL-FRANCE:TWA 2 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg/m3 JAN 1993 OEL-RUSSIA:STEL 0.3 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO CESIUM HYDROXIDE-air:10H TWA 2.0 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992
氢氧化铯 溶液安全信息
[ 符号 ]:
GHS05, GHS07
[ 信号词 ]:
Danger
[ 危害声明 ]:
H302-H314
[ 警示性声明 ]:
P280-P305 + P351 + P338-P310
[ 危害码 (欧洲) ]:
C:Corrosive
[ 风险声明 (欧洲) ]:
R22;R35
[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S37/39-S27-S28
[ 危险品运输编码 ]:
UN 2682 8/PG 2
[ WGK德国 ]:
3
[ 包装等级 ]:
II
[ 危险类别 ]:
8
[ 海关编码 ]:
2825909000
氢氧化铯 溶液制备
将氢氧化钡的水溶液与等当量的硫酸铯作用。滤液在装有固体氢氧化钾的干燥器中真空浓缩,即可得到氢氧化铯。
氢氧化铯 溶液海关
[ 海关编码 ]: 2825909000
氢氧化铯 溶液文献
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 152 , 165-71, (2015)
In the present work, isopropyl-6-amino-4-(3,5-bis(trifluoromethyl)phenyl)-5-cyano-2-methyl-4H-pyran-3-carboxylate (4H-pyran analog) has been synthesized by a three component reaction catalyzed by CsOH...
Behrens, E.A. et al.Chem. Mater. 8 , 1236, (1996)
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