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2-二环己膦基-2'-(N,N-二甲胺)-联苯

2-二环己膦基-2'-(N,N-二甲胺)-联苯用途

DavePhos是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

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2-二环己膦基-2'-(N,N-二甲胺)-联苯名称

[ CAS 号 ]:
213697-53-1

[ 中文名 ]:
2-二环己膦基-2'-(N,N-二甲胺)-联苯

[ 英文名 ]:
2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl

[中文别名 ]:

[英文别名 ]:

Buchwald's DavePhos ligand
2-dimethylamino-2'-(dicyclohexylphosphino)biphenyl
2-Dimethylamino-2'-dicyclohexylphosphinobiphenyl
2-(3-METHOXYPROPOXY)-5-METHYLANILINE
DavePhos
MFCD02183572

2-二环己膦基-2'-(N,N-二甲胺)-联苯生物活性

[ 描述 ]:

DavePhos是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

2-二环己膦基-2'-(N,N-二甲胺)-联苯物理化学性质

[ 沸点 ]:
539.6±43.0 °C at 760 mmHg

[ 熔点 ]:
121-124 °C(lit.)

[ 分子式 ]:
C₂₆H₃₆NP

[ 分子量 ]:
393.54

[ 闪点 ]:
280.1±28.2 °C

[ 精确质量 ]:
393.258545

[ PSA ]:
16.83000

[ LogP ]:
8.56

[ 外观性状 ]:
白色至淡黄色晶体

[ 蒸汽压 ]:
0.0±1.4 mmHg at 25°C

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)

[ 水溶解性 ]:
Insoluble

2-二环己膦基-2'-(N,N-二甲胺)-联苯MSDS

2-二环己膦基-2'-(N,N-二甲胺)-联苯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

2-二环己膦基-2'-(N,N-二甲胺)-联苯合成路线

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2-二环己膦基-2'-(N,N-二甲胺)-联苯文献

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...

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