庚烯磷
庚烯磷用途
庚烯磷名称
[ CAS 号 ]:
23560-59-0
[ 中文名 ]:
庚烯磷
[ 英文名 ]:
heptenophos
[中文别名 ]:
[英文别名 ]:
- HOE 2982 OJ
- Hostavik [Russian]
- HEPTENOPHOS
- EINECS 245-737-0
- XOE 2982 [Russian]
- Heptenophos [BSI:ISO]
- Ragadan
- Caswell No. 721C
庚烯磷物理化学性质
[ 密度 ]:
1.36g/cm3
[ 沸点 ]:
289.3ºC at 760mmHg
[ 熔点 ]:
25°C
[ 分子式 ]:
C9H12ClO4P
[ 分子量 ]:
250.61600
[ 闪点 ]:
160.2ºC
[ 精确质量 ]:
250.01600
[ PSA ]:
54.57000
[ LogP ]:
3.06020
[ 外观性状 ]:
liquid
[ 蒸汽压 ]:
0.004mmHg at 25°C
[ 折射率 ]:
1.518
[ 储存条件 ]:
APPROX 4°C
庚烯磷MSDS
庚烯磷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TB8545000
- CHEMICAL NAME :
- Phosphoric acid, (7-chloro-bicyclo(3.2.0)hepta-2,6-dien-6-yl) dimethyl ester
- CAS REGISTRY NUMBER :
- 23560-59-0
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 11
- MOLECULAR FORMULA :
- C9-H12-Cl-O4-P
- MOLECULAR WEIGHT :
- 250.63
- WISWESSER LINE NOTATION :
- L45 BU EUTJ BOPO&O1&O1 CG
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 96 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 1,11,1977
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 400 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A226,1983
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2 gm/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - muscle contraction or spasticity Gastrointestinal - hypermotility, diarrhea
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(4),18,1984
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 2 gm/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - muscle contraction or spasticity Gastrointestinal - hypermotility, diarrhea
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(4),18,1984
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 75 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- TGANAK Tsitologiya i Genetika. Cytology and Genetics. For English translation, see CYGEDX. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1967- Volume(issue)/page/year: 16(1),45,1982
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- >500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- SPEADM Special Publication of the Entomological Society of America. (4603 Calvert Rd., College Park, MD 20740) Volume(issue)/page/year: 78-1,39,1978
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - quail
- DOSE/DURATION :
- 17 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,467,1991
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 379 mg/m3
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 55(5),72,1990
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 117 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- KSKZAN Khimiya v Sel'skom Khozyaistve. Chemistry in Agriculture. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) No.1- 1963- Volume(issue)/page/year: 16(2),59,1978 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 140 mg/kg/10D-I
- TOXIC EFFECTS :
- Biochemical - Neurotransmitters or modulators (putative) - catecholamine levels in CNS Biochemical - Neurotransmitters or modulators (putative) - dopamine at other sites
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(5),80,1984
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 378 mg/kg/12W-C
- TOXIC EFFECTS :
- Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 49(4),18,1984
庚烯磷安全信息
[ 符号 ]:
GHS06, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H301-H312-H330-H410
[ 警示性声明 ]:
P260-P273-P284-P301 + P310 + P330-P304 + P340 + P310-P403 + P233
[ 危害码 (欧洲) ]:
T,N,Xn,F
[ 风险声明 (欧洲) ]:
25-50/53-52/53-36-20/21/22-11
[ 安全声明 (欧洲) ]:
S23;S26;S28;S37;S45;S60;S61;S36/S37
[ 危险品运输编码 ]:
UN 3018
[ RTECS号 ]:
TB8545000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1(b)
[ 海关编码 ]:
2919900035
庚烯磷制备
1.二氯乙酰氯的制备 往反应瓶中加入二氯乙酸，在加热下滴加邻苯二甲酰氯，滴加毕，升温分馏，收集106-110℃馏分即得。2.7，7-二氯二环[ 3.2.0 ]庚-2-烯-6-酮的制备 在反应瓶中混合二氯乙酰氯、新鲜解聚得到的环戊二烯及戊烷组成的溶液。在氮气下搅拌加热回流并慢慢滴加三乙胺的戊烷溶液。加毕后回流几小时，得乳白色液。加入蒸馏水，以溶解三乙胺盐酸盐。分出水层，水层用戊烷抽提，合并有机层，经干燥、过滤，蒸去戊烷及多余的环戊二烯后，得粘稠的橙色液体，减压蒸馏，收集66-68℃（0.267kPa）的馏分即得。3.庚烯磷的制备 在反应瓶中加入7，7-二氯二环[3.2.0]庚-2-烯-6-酮及亚磷酸三甲酯，加热至适当温度后再保温反应几小时，然后减压蒸馏收集128-130℃（0.53kPa）馏分即得。配制成40%可湿性粉剂或25%、50%乳剂。
庚烯磷海关
[ 海关编码 ]: 2919900090
[ 中文概述 ]:
HS:2919900090 其他磷酸酯及其盐（包括乳磷酸盐）（包括它们的卤化，磺化，硝化和亚硝化衍生物） 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单
[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验
[ Summary ]:
2919900090 other phosphoric esters and their salts, including lactophosphates; their halogenated, sulphonated, nitrated or nitrosated derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%
庚烯磷文献
Gig. Sanit. (1) , 57-9, (1990)
推荐生产厂家/供应商：
公司名：上海化源世纪贸易有限公司
区域：上海市普陀区
价格：
联系人：徐经理
产品详情：庚烯磷
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥4739.0/500mg
￥需询单/1g
￥需询单/1g
￥需询单/1g
联系人：阿拉丁
产品详情：庚磷
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相关化合物
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