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2-二苯基膦-2'-(N组,n-二甲胺基)-联苯

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯用途

作为配体，用于Buchwald, Heck等偶联反应中

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2-二苯基膦-2'-(N组,n-二甲胺基)-联苯名称

[ CAS 号 ]:
240417-00-9

[ 中文名 ]:
2-二苯基磷-2'-(N,N-二甲氨基)联苯

[ 英文名 ]:
PhDavePhos

[中文别名 ]:

[英文别名 ]:

PhDave-Phos
2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl
MFCD03094578
RW2172
2-Diphenylphosphino-2`-dimethylaminobiphenyl
2-Ph2P-2'-(Me2N)biphenyl
PhDavePhos
2-Diphenylphosphino-2‘-(N,N-dimethylamino)biphenyl
2-Dimethylamino-2'-(diphenylphosphino)biphenyl

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯物理化学性质

[ 沸点 ]:
514.6±43.0 °C at 760 mmHg

[ 熔点 ]:
126-128 °C

[ 分子式 ]:
C₂₆H₂₄NP

[ 分子量 ]:
381.449

[ 闪点 ]:
265.0±28.2 °C

[ 精确质量 ]:
381.164642

[ PSA ]:
16.83000

[ LogP ]:
7.56

[ 外观性状 ]:
白色至黄色粉末,晶体,结晶

[ 蒸汽压 ]:
0.0±1.3 mmHg at 25°C

[ 储存条件 ]:
2~8℃，干燥，密封

[ 水溶解性 ]:
不溶

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯MSDS

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
37/39-26-36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
NM1880000

[ 海关编码 ]:
2921499090

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯合成路线

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯上下游产品

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯上游产品

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯下游产品

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯海关

[ 海关编码 ]: 2921499090

[ 中文概述 ]:
2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

2-二苯基膦-2'-(N组,n-二甲胺基)-联苯文献

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...

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