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4-硝基苯硼酸

4-硝基苯硼酸用途

4-硝基苯硼酸是一种生物化学试剂,可作为生物材料或有机化合物进行生命科学相关研究。

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4-硝基苯硼酸名称

[ CAS 号 ]:
24067-17-2

[ 中文名 ]:
4-硝基苯基硼酸

[ 英文名 ]:
(4-Nitrophenyl)boronic acid

[中文别名 ]:

4-硝基苯硼酸

[英文别名 ]:

Phenylboronic Acid,9
(4-Nitrophenyl)boronic acid
para-nitrophenylboronic acid
phenylboronic acid pinacol ester
4-Nitrobenzeneboronic Acid
MFCD00161360
boronic acid,b-(4-nitrophenyl)
4-Borononitrobenzene
Boronic acid, B-(4-nitrophenyl)-
p-nitrophenylboronic acid

4-硝基苯硼酸生物活性

[ 描述 ]:

4-硝基苯硼酸是一种生物化学试剂,可作为生物材料或有机化合物进行生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[体外研究]

4-硝基苯硼酸是一种芳基硼酸,已被用于合成苯酚。

[参考文献]

[1]. Xu, J., Wang, X., Shao, C., et al.Highly efficient synthesis of phenols by copper- catalyzed oxidative hydroxylation of arylboronic acids at room temperature in waterOrg. Lett.12(9)1964-1967(2010)

[2]. Sawant, SD, Hudwekar, AD, Kumar, KAA, et al.Ligand- and base-free synthesis of phenols by rapid oxidation of arylboronic acids using iron(III) oxideTetrahedron Lett.55(4)811-814(2014)

4-硝基苯硼酸物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
373.7±44.0 °C at 760 mmHg

[ 熔点 ]:
285-290°C (dec.)

[ 分子式 ]:
C₆H₆BNO₄

[ 分子量 ]:
166.93

[ 闪点 ]:
179.8±28.4 °C

[ 精确质量 ]:
167.038986

[ PSA ]:
86.28000

[ LogP ]:
1.32

[ 外观性状 ]:
固体;White to Green to Brown powder to crystal

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.574

[ 储存条件 ]:
2~8℃

[ 水溶解性 ]:
水溶性：不溶；可溶于：甲醇

4-硝基苯硼酸MSDS

4-硝基苯硼酸安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S26-S36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ 海关编码 ]:
2931900090

4-硝基苯硼酸合成路线

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4-硝基苯硼酸下游产品

4-硝基苯硼酸海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

4-硝基苯硼酸文献

Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates.

Org. Lett. 7th ed., 14 , 1930-1933, (2012)

A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combin...

A new access to 3-substituted-1(2H)-isoquinolone by tandem palladium-catalyzed intramolecular aminocarbonylation annulation.

Org. Biomol. Chem. 13th ed., 10 , 2683-2691, (2012)

An original tribromide derivative based, palladium-catalyzed synthesis of 3-substituted-1(2H)-isoquinolone is described based on a regioselective Suzuki-Miyaura C-C coupling on o-halo-(2,2-dihalovinyl...

Copper-mediated sequential cyanation of aryl C-B and arene C-H bonds using ammonium iodide and DMF.

J. Am. Chem. Soc. 5th ed., 134 , 2528-2531, (2012)

The cyanation of aromatic boronic acids, boronate esters, and borate salts was developed under copper-mediated oxidative conditions using ammonium iodide and DMF as the source of nitrogen and carbon a...

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