异十三吗啉
异十三吗啉用途
1.吗啉类杀菌剂，兼有保护、治疗和内吸作用，残效长，对作物无药害，用于防治大麦、小麦的白粉病，小麦叶锈病、条锈病，黄瓜、马铃薯、橡胶、豌豆的白粉病。
2.用作医药中间体
异十三吗啉名称
[ CAS 号 ]:
24602-86-6
[ 中文名 ]:
异十三吗啉
[ 英文名 ]:
Tridemorph
[中文别名 ]:
[英文别名 ]:
- TRIDEMORPN
- 2,6-Dimethyl-N-tridecylmorpholine
- N-Tridecyl-2,6-dimethylmorpholine
- bas2205-f
- e-236
- BAFS 220F
- Morpholine, 2,6-dimethyl-4-tridecyl-
- Basf 220f
- CALAXIN
- 2,6-Dimethyl-4-tridecyltetrahydro-1,4-oxazine
异十三吗啉物理化学性质
[ 密度 ]:
0.9±0.1 g/cm3
[ 沸点 ]:
371.3±17.0 °C at 760 mmHg
[ 分子式 ]:
C19H39NO
[ 分子量 ]:
297.519
[ 闪点 ]:
109.5±23.3 °C
[ 精确质量 ]:
297.303162
[ PSA ]:
12.47000
[ LogP ]:
7.03
[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C
[ 折射率 ]:
1.449
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
异十三吗啉MSDS
异十三吗啉毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- QE2705000
- CHEMICAL NAME :
- Morpholine, 2,6-dimethyl-N-tridecyl-
- CAS REGISTRY NUMBER :
- 24602-86-6
- LAST UPDATED :
- 199706
- DATA ITEMS CITED :
- 11
- MOLECULAR FORMULA :
- C19-H39-N-O
- MOLECULAR WEIGHT :
- 297.59
- WISWESSER LINE NOTATION :
- T6N DOTJ A13 C1 F1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 650 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,522,1973
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1560 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 39(6),55,1981
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - cat
- DOSE/DURATION :
- 540 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 39(6),55,1981
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 750 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 5,229,1976
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 1 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 39(6),55,1981 ** REPRODUCTIVE DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 1300 mg/kg
- SEX/DURATION :
- female 1-20 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - homeostasis
- REFERENCE :
- VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 39(6),55,1981
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 5400 ug/kg
- SEX/DURATION :
- female 7-15 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - other developmental abnormalities
- REFERENCE :
- VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 38(6),51,1980
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 29250 ug/kg
- SEX/DURATION :
- female 7-15 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - Central Nervous System Reproductive - Specific Developmental Abnormalities - urogenital system
- REFERENCE :
- VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 39(6),55,1981
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 585 mg/kg
- SEX/DURATION :
- female 7-15 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
- REFERENCE :
- VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 39(6),55,1981
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 5400 ug/kg
- SEX/DURATION :
- female 7-15 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - cardiovascular (circulatory) system
- REFERENCE :
- VPITAR Voprosy Pitaniya. Problems of Nutrition. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1932-41; V.11- 1952- Volume(issue)/page/year: 39(6),55,1981
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- DOSE :
- 2451 mg/kg
- SEX/DURATION :
- female 6-15 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
- REFERENCE :
- TJADAB Teratology, The International Journal of Abnormal Development. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968- Volume(issue)/page/year: 29,259,1984
异十三吗啉安全信息
[ 符号 ]:
GHS07, GHS08, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H302-H315-H332-H360D-H410
[ 警示性声明 ]:
P201-P273-P308 + P313-P501
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
T:Toxic; N:Dangerous for the environment;
[ 风险声明 (欧洲) ]:
R20/22;R38;R50/53;R61
[ 安全声明 (欧洲) ]:
S45-S53-S60-S61
[ 危险品运输编码 ]:
UN 3082
[ RTECS号 ]:
QE2705000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1(b)
[ 海关编码 ]:
2934999035
异十三吗啉制备
由N，N-双（β-羟丙基）十三胺在硫酸存在下，于160℃脱水环合制得。
异十三吗啉海关
[ 海关编码 ]: 2934999035
[ 中文概述 ]:
2934999035 十二环吗啉,十三吗啉。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ 监管条件 ]: S.进出口农药登记证明
[ Summary ]:
2934999035 2,6-dimethyl-4-tridecylmorpholine。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%
异十三吗啉文献
Steroids 53(3-5) , 393-412, (1989)
The effect of five sterol-biosynthesis-inhibiting (SBI) fungicides, triadimefon, triarimol, diclobutrazol, tridemorph, and fenpropimorph on the germination, growth, and chloroplast pigment and sterol ...
[Teratogenic effect of the fungicide calixin].Vopr. Pitan. (6) , 55-61, (1981)
Experimental studies on Wistar rats revealed that the fungicide calixin (N-tridecyl-2.6-dimethylmorpholine) has a teratogenic effect. This effect manifested in edemas, hemorrhages, hematomas, abnormal...
Human lamin B receptor exhibits sterol C14-reductase activity in Saccharomyces cerevisiae.Biochim. Biophys. Acta 1392(2-3) , 233-44, (1998)
Lamin B receptor (LBR), a nuclear protein of avian and mammalian cells, contains an hydrophobic domain that shares extensive structural similarities with the members of the sterol reductase family. To...
相关化工产品/化学物质：
推荐生产厂家/供应商：
公司名：上海化源世纪贸易有限公司
区域：上海市普陀区
价格：
联系人：徐经理
产品详情：2,6-二甲基-4-十三烷基吗啉
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥608.0/250mg
联系人：刘佳
产品详情：2,6-二甲基-4-十三烷基吗啉
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥448.0/250mg
￥需询单/1g
￥需询单/1g
￥需询单/1g
联系人：阿拉丁
产品详情：2,6-二甲基-4-十三烷基吗啉
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相关化合物
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