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1-乙酰基咪唑

1-乙酰基咪唑用途

【用途一】
用作医药中间体
【用途二】
作乙酰化试剂,供生化研究用。
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1-乙酰基咪唑名称

[ CAS 号 ]:
2466-76-4

[ 中文名 ]:
1-乙酰基咪唑

[ 英文名 ]:
1-acetylimidazole

[中文别名 ]:

[英文别名 ]:

1-乙酰基咪唑物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
222.0±23.0 °C at 760 mmHg

[ 熔点 ]:
99-105 °C(lit.)

[ 分子式 ]:
C5H6N2O

[ 分子量 ]:
110.114

[ 闪点 ]:
88.0±22.6 °C

[ 精确质量 ]:
110.048012

[ PSA ]:
34.89000

[ LogP ]:
-0.34

[ 外观性状 ]:
白色至淡黄色晶体

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.552

[ 储存条件 ]:
库房通风低温干燥

1-乙酰基咪唑MSDS

1-乙酰基咪唑毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NI3400000
CHEMICAL NAME :
Imidazole, 1-acetyl-
CAS REGISTRY NUMBER :
2466-76-4
BEILSTEIN REFERENCE NO. :
0108425
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C5-H6-N2-O
MOLECULAR WEIGHT :
110.13
WISWESSER LINE NOTATION :
T5N CNJ AV1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Immunological Including Allergic - decreased immune response
REFERENCE :
StoGD# Personal Communication from G.D. Stoner, Dept. of Community Medicine, School of Medicine, Univ. of California, La Jolla, CA 92037, May 25, 1975 Volume(issue)/page/year: 27MAY1975 ** TUMORIGENIC DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
50 mg/kg/I
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors
REFERENCE :
JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 54,495,1975
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1-乙酰基咪唑安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
NI3400000

[ 海关编码 ]:
2933290090

1-乙酰基咪唑上下游产品

1-乙酰基咪唑制备

1.咪唑与乙酸异丙烯酯反应在50毫升圆烧瓶中,加入0.2g(0.03mol)咪唑,20ml乙酸异丙烯酯和几滴浓硫酸。将混合物在60℃保温1h。蒸馏除去少量的乙酸异丙烯酯和丙酮。剩余物用水碳酸钠处理。倾出液体。在空气浴中蒸发至干。得粗品3.1g,产率94%,熔点93-96℃。现经乙酸异丙烯酯重结晶,熔点达到101.5102.5℃。

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1-乙酰基咪唑海关

[ 海关编码 ]: 2933290090

[ 中文概述 ]:
2933290090. 其他结构含非稠合咪唑环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期

[ Summary ]:
2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1-乙酰基咪唑文献

Involvement of conserved histidine, lysine and tyrosine residues in the mechanism of DNA cleavage by the caspase-3 activated DNase CAD.

Nucleic Acids Res. 30(6) , 1325-32, (2002)

The caspase-activated DNase (CAD) is involved in DNA degradation during apoptosis. Chemical modification of murine CAD with the lysine-specific reagent 2,4,6-trinitrobenzenesulphonic acid and the tyro...

Changes in the level and activation state of the plasma membrane H(+)-ATPase during aging of red beet slices.

Plant Physiol. 114(3) , 857-62, (1997)

The effect of aging on the plasma membrane (PM) H(+)-ATPase of red beet (Beta vulgaris L.) parenchyma discs was analyzed in PM purified by aqueous two-phase partitioning. Aging increased both the acti...

Chemical modification of active site residues in gamma-glutamyl transpeptidase. Aspartate 422 and cysteine 453.

J. Biol. Chem. 270(21) , 12476-80, (1995)

gamma-Glutamyl transpeptidase, an enzyme of central significance in glutathione metabolism, is inactivated by iodoacetamide, which esterifies an active site carboxyl group identified here as that of A...


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产品详情:1-乙酰基咪唑


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【1-乙酰基咪唑】化源网提供1-乙酰基咪唑CAS号2466-76-4,1-乙酰基咪唑MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询1-乙酰基咪唑上化源网,专业又轻松。>>电脑版:1-乙酰基咪唑

标题:1-乙酰基咪唑_MSDS_用途_密度_CAS号【2466-76-4】_化源网 地址:https://m.chemsrc.com/mip/cas/2466-76-4_335807.html