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2-(二环己基膦基)联苯

2-(二环己基膦基)联苯用途

【用途一】
作为配体，用于偶联反应、氧化、取代、环加成反应中

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2-(二环己基膦基)联苯名称

[ CAS 号 ]:
247940-06-3

[ 中文名 ]:
2-(二环己基膦基)联苯

[ 英文名 ]:
2-(Dicyclohexylphosphino)biphenyl

[中文别名 ]:

[英文别名 ]:

(2-Biphenyl)dicyclohexylphosphine
(2-Biphenylyl)dicyclohexylphosphine
Biphenyl-2-yl(dicyclohexyl)phosphine
biphenyl-2-yl-dicyclohexyl-phosphane
2-(Dicyclohexylphosphino)Biphenyl
2-dicyclohexylphosphino-1,1'-biphenyl
EINECS 480-030-2
2-Biphenylyl(dicyclohexyl)phosphine
Phosphine, [1,1'-biphenyl]-2-yldicyclohexyl-
P,P-dicyclohexyl-o-biphenylphosphine

2-(二环己基膦基)联苯生物活性

[ 描述 ]:

Cyjohnphos是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

2-(二环己基膦基)联苯物理化学性质

[ 沸点 ]:
499.5±24.0 °C at 760 mmHg

[ 熔点 ]:
102-106 °C(lit.)

[ 分子式 ]:
C₂₄H₃₁P

[ 分子量 ]:
350.48

[ 闪点 ]:
271.7±29.2 °C

[ 精确质量 ]:
350.216339

[ PSA ]:
13.59000

[ LogP ]:
8.45

[ 外观性状 ]:
白色至淡黄色晶体粉末

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)

[ 水溶解性 ]:
可溶于：甲苯

2-(二环己基膦基)联苯MSDS

2-(二环己基膦基)联苯安全信息

[ 危害声明 ]:
H413

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xn: Harmful;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S36/37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2902909090

2-(二环己基膦基)联苯合成路线

2-(二环己基膦基)联苯上下游产品

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2-(二环己基膦基)联苯下游产品

2-(二环己基膦基)联苯海关

[ 海关编码 ]: 2902909090

[ 中文概述 ]:
2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

2-(二环己基膦基)联苯文献

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...

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