异柳磷
异柳磷用途
异柳磷名称
[ CAS 号 ]:
25311-71-1
[ 中文名 ]:
异柳磷
[ 英文名 ]:
UNII:0514MAW53A
[中文别名 ]:
[英文别名 ]:
- pyrfon
- Amidocid
- Amaze
- ISOFENPHOS
- EINECS 246-814-1
- Pryfon
- [14C]-Isofenphos
- discus
- AMAZE(R)
- 40sd
异柳磷物理化学性质
[ 密度 ]:
1.2±0.1 g/cm3
[ 沸点 ]:
411.5±47.0 °C at 760 mmHg
[ 熔点 ]:
Less than -12ºC
[ 分子式 ]:
C15H24NO4PS
[ 分子量 ]:
345.394
[ 闪点 ]:
202.7±29.3 °C
[ 精确质量 ]:
345.116364
[ PSA ]:
98.69000
[ LogP ]:
4.12
[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C
[ 折射率 ]:
1.528
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
异柳磷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- VO4395500
- CHEMICAL NAME :
- Salicylic acid, isopropyl ester, O-ester with O-ethyl isopropylphosphoramidothioate
- CAS REGISTRY NUMBER :
- 25311-71-1
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 10
- MOLECULAR FORMULA :
- C15-H24-N-O4-P-S
- MOLECULAR WEIGHT :
- 345.43
- WISWESSER LINE NOTATION :
- 1Y1&OVR DOPS&O2&MY1&1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 28 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revision Volume(issue)/page/year: 1,118,1977
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 144 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A236,1983
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 188 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- SPEADM Special Publication of the Entomological Society of America. (4603 Calvert Rd., College Park, MD 20740) Volume(issue)/page/year: 78-1,39,1978
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 91300 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976 Volume(issue)/page/year: -,-,1971/1976
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 162 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C173,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - chicken
- DOSE/DURATION :
- 3 mg/kg
- TOXIC EFFECTS :
- Behavioral - tremor Behavioral - muscle weakness Gastrointestinal - changes in structure or function of salivary glands
- REFERENCE :
- BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 33,386,1984
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - quail
- DOSE/DURATION :
- 13 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea
- REFERENCE :
- EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 8,551,1984 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2240 mg/kg/8W-I
- TOXIC EFFECTS :
- Liver - other changes Biochemical - Metabolism (Intermediary) - other proteins
- REFERENCE :
- IJEBA6 Indian Journal of Experimental Biology. (Publications & Information Directorate, CSIR, Hillside Rd., New Delhi 110 012, India) V.1- 1963- Volume(issue)/page/year: 21,684,1983 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989
异柳磷安全信息
[ 符号 ]:
GHS02, GHS07
[ 信号词 ]:
Danger
[ 危害声明 ]:
H225-H302 + H312 + H332-H319-H412
[ 警示性声明 ]:
P210-P273-P280-P305 + P351 + P338
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
T: Toxic;N: Dangerous for the environment;
[ 风险声明 (欧洲) ]:
24/25-50/53
[ 安全声明 (欧洲) ]:
S36/37-S45-S60-S61
[ 危险品运输编码 ]:
3018
[ RTECS号 ]:
VO4395500
[ 包装等级 ]:
I
[ 危险类别 ]:
6.1(a)
[ 海关编码 ]:
2929909012
异柳磷制备
由乙基硫磷酰二氯、水杨酸异丙酯、异丙胺经下列反应而得。将水杨酸异丙酯、乙基硫代磷酰二氯和催化剂投入反应釜，搅拌冷却至 10 ℃ 左右。缓慢加入一部分氢氧化钠溶液，反应半小时后再将其余的氢氧化钠溶液和异丙胺同时缓慢均匀加入。加毕后再继续反应2h。然后加水和溶剂，搅拌后静置分出下层废水，上层粗油经减压蒸馏即得乙基异柳磷原油。将乙基硫代磷酰二氯用甲基硫代磷酰二氯代替，采用相似工艺可制得甲基异柳磷。原料消耗定额：水杨酸 350kg /t、异丙醇 580kg /t、硫酸 340kg /t、甲醇 720kg /t、异丙胺 130kg /t、三氯硫磷 380kg /t。
异柳磷海关
[ 海关编码 ]: 2929909012
[ 中文概述 ]:
2929909012 异柳磷、甲基异柳磷、丙胺氟磷等 退税率:0.0% 监管条件:S(进出口农药登记证明)
[ 申报要素 ]: 品名, 成分含量, 用途
[ 监管条件 ]: S.进出口农药登记证明
[ Summary ]:
2929909012 isopropyl 2-((ethoxy(isopropylamino)phosphorothioyl)oxy)benzoate
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