4-硝基间甲苯酚

【用途一】
用作医药中间体
【用途二】
对硝基间甲酚又称3-甲基-4-硝基苯酚(3-methyl-4-nitrophenol)，简称4-硝，是有机磷杀虫剂杀螟硫磷的中间体。
【用途三】
用途较广，主要用来制造农药杀螟松（一种高效、低毒、低残留的优良有机磷杀虫剂）。

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
304.9±30.0 °C at 760 mmHg

[ 熔点 ]:
125-130 °C(lit.)

[ 分子式 ]:
C₇H₇NO₃

[ 分子量 ]:
153.135

[ 闪点 ]:
140.0±13.0 °C

[ 精确质量 ]:
153.042587

[ PSA ]:
66.05000

[ LogP ]:
2.03

[ 外观性状 ]:
米色粉末

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.597

[ 储存条件 ]:
室温，干燥

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

GP2625000

CHEMICAL NAME :

m-Cresol, 4-nitro-

CAS REGISTRY NUMBER :

2581-34-2

BEILSTEIN REFERENCE NO. :

1868105

LAST UPDATED :

199701

DATA ITEMS CITED :

5

MOLECULAR FORMULA :

C7-H7-N-O3

MOLECULAR WEIGHT :

153.15

WISWESSER LINE NOTATION :

WNR DQ B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

1200 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

90 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intracerebral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

15 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TEST SYSTEM :

Rodent - mouse

DOSE/DURATION :

2500 mg/kg/10W (Intermittent)

REFERENCE :

EESADV Ecotoxicology and Environmental Safety. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1977- Volume(issue)/page/year: 9,47,1985

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H312-H315-H319-H332-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37-S37/39

[ 危险品运输编码 ]:
UN 2446 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
GP2625000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

[ 海关编码 ]:
29089000

详细合成路线

4-硝基间甲苯酚上游产品

4-硝基间甲苯酚下游产品

以间甲酚为原料，可用亚硝化氧化法或直接硝化法制取。

[ 海关编码 ]: 2908999090

[ 中文概述 ]:
2908999090 其他酚及酚醇的卤化等衍生物（包括其磺化、硝化或亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2908999090 halogenated, sulphonated, nitrated or nitrosated derivatives of phenols or phenol-alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Improvement of an efficient separation method for chemicals in diesel exhaust particles: analysis for nitrophenols.

Environ. Sci. Pollut. Res. Int. 15(4) , 318-21, (2008)

Diesel exhaust is believed to consist of thousands of organic constituents and is a major cause of urban pollution. We recently reported that a systematic separation procedure involving successive sol...

Measurement of nitrophenols in rain and air by two-dimensional liquid chromatography-chemically active liquid core waveguide spectrometry.

Anal. Chem. 82(13) , 5838-43, (2010)

We report a novel system to analyze atmospheric nitrophenols (NPs). Rain or air sample extracts (1 mL) are preconcentrated on a narrow bore (2 mm) aliphatic anion exchanger. In the absence of strong r...

New analytical method for sensitive quantification of urinary 3-methyl-4-nitrophenol to assess fenitrothion exposure in general population and occupational sprayers.

Toxicol. Lett. 210(2) , 220-4, (2012)

The measurement of blood cholinesterase (ChE) activities is adopted worldwide for biological monitoring of exposure to organophosphorus insecticides (OPs). Recent development of analytical chemistry h...

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公司名：上海化源生化科技有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：4-硝基间甲苯酚

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥118.0/10g

联系人：刘佳

产品详情：4-硝基间甲苯酚

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥288.9/100g ￥49.9/10g ￥576.9/250g ￥90.9/25g

联系人：阿拉丁

产品详情：4-硝基间甲酚

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