杀螟腈

杀螟腈用途

1.用于防治果树、蔬菜和观赏植物上的鳞翅目害虫，也可防治蟑螂、苍蝇和蚊子之类的卫生害虫。

2.用于防治二化螟、三化螟、纵卷叶螟、稻苞虫、稻叶蝉、稻蓟马、黏虫、蚜虫、黄条跳甲、叶螨等，也能防治果树、蔬菜和观赏植物上的鳞翅害虫，苍蝇、蚊子等卫生害虫。制成毒饵并撒于土中可防治地老虎。使用浓度为25～50g有效成分/100kg水。

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杀螟腈名称

[ CAS 号 ]:
2636-26-2

[ 中文名 ]:
杀螟睛

[ 英文名 ]:
cyanophos

[中文别名 ]:

[英文别名 ]:

Caswell No. 268A
Sumitomo S 4084
Sunitomo S 4084
Ciafos
Cyanox
4-dimethoxyphosphinothioyloxybenzonitrile
O-(4-Cyanphenyl)-O,O-dimethylthiophosphat
Cynock
cyanophos
O-4-cyanophenyl O,O-dimethyl phosphorothioate

杀螟腈物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
322.3±44.0 °C at 760 mmHg

[ 熔点 ]:
14-15ºC

[ 分子式 ]:
C₉H₁₀NO₃PS

[ 分子量 ]:
243.219

[ 闪点 ]:
148.7±28.4 °C

[ 精确质量 ]:
243.011902

[ PSA ]:
93.38000

[ LogP ]:
2.71

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.554

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

杀螟腈MSDS

详细MSDS(安全技术说明书)

杀螟腈毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TF7600000

CHEMICAL NAME :: Phosphorothioic acid, O,O-dimethyl ester, O-ester with p-hydroxybenzonitrile

CAS REGISTRY NUMBER :: 2636-26-2

LAST UPDATED :: 199612

DATA ITEMS CITED :: 12

MOLECULAR FORMULA :: C9-H10-N-O3-P-S

MOLECULAR WEIGHT :: 243.23

WISWESSER LINE NOTATION :: NCR DOPS&O1&O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 215 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ABCHA6 Agricultural and Biological Chemistry. (Maruzen Co. Ltd., POB 5050, Tokyo International, Tokyo 100-31, Japan) V.25- 1961- Volume(issue)/page/year: 26,257,1962

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 5,62,1976

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 720 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 37,427,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ABCHA6 Agricultural and Biological Chemistry. (Maruzen Co. Ltd., POB 5050, Tokyo International, Tokyo 100-31, Japan) V.25- 1961- Volume(issue)/page/year: 26,257,1962

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 350 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ABCHA6 Agricultural and Biological Chemistry. (Maruzen Co. Ltd., POB 5050, Tokyo International, Tokyo 100-31, Japan) V.25- 1961- Volume(issue)/page/year: 26,257,1962

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1080 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ABCHA6 Agricultural and Biological Chemistry. (Maruzen Co. Ltd., POB 5050, Tokyo International, Tokyo 100-31, Japan) V.25- 1961- Volume(issue)/page/year: 26,257,1962

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: 23500 ug/kg

TOXIC EFFECTS :: Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - convulsions or effect on seizure threshold Behavioral - ataxia

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 11,49,1967

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 2010 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 21(7),34,1977

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - wild bird species

DOSE/DURATION :: 3 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JTCEEM Journal de Toxicologie Clinique et Experimentale. (SPPIF, B.P.22, F-41353 Vineuil, France) V.5- 1985- Volume(issue)/page/year: 6(3),175,1986 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 365 mg/kg/1Y-I

TOXIC EFFECTS :: Behavioral - alteration of operant conditioning

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 48(9),76,1983

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: 980 mg/kg/2W-C

TOXIC EFFECTS :: Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 11,,49,1967 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3 JAN 1993

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杀螟腈安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302 + H312-H410

[ 警示性声明 ]:
P273-P280-P501

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R21/22

[ 安全声明 (欧洲) ]:
36/37-60-61

[ 危险品运输编码 ]:
3018

[ RTECS号 ]:
TF7600000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2926909032

杀螟腈制备

由O,O-二甲基氯代硫逐磷酸酯与氰基酚反应得到。原药含量约93%，每吨产品消耗4-氰基苯酚530kg，无水碳酸钾620kg，O,O-二甲基硫逐磷酰氯720kg，其中4-氰基苯酚由对羟基苯甲酸与尿素、五硫化二磷于50-300℃反应制得。

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杀螟腈海关

[ 海关编码 ]: 2926909032

[ 中文概述 ]:
2926909032 杀螟腈、甲基辛硫磷等〔包括敌草腈、碘苯腈、辛酰碘苯腈、溴苯腈、辛酰溴苯腈〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2926909032 o-(4-cyanophenyl) o,o-dimethyl phosphorothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

杀螟腈文献

Development of phage immuno-loop-mediated isothermal amplification assays for organophosphorus pesticides in agro-products.

Anal. Chem. 86(16) , 8441-7, (2014)

Two immuno-loop-mediated isothermal amplification assays (iLAMP) were developed by using a phage-borne peptide that was isolated from a cyclic eight-peptide phage library. One assay was used to screen...

[Health standardization of Cyanox in water].

Gig. Sanit. (9) , 76-7, (1983)

[Contamination of sugar cane by 2 bird poisons: fenthion and cyanophos. Evaluation of residues in sugar cane juice transformed into sugar].

Dakar Med. 29(2) , 383-90, (1984)

更多文献

杀螟腈

杀螟腈用途

杀螟腈名称

杀螟腈物理化学性质

杀螟腈MSDS

详细MSDS(安全技术说明书)

杀螟腈毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

杀螟腈安全信息

杀螟腈制备

杀螟腈海关

杀螟腈文献

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