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益棉磷

益棉磷用途

【用途一】
该品为有机磷杀虫杀螨剂,有很好的稳定性和持久性,主要用于防治棉花、果树、蔬菜等作物的害虫。
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益棉磷名称

[ CAS 号 ]:
2642-71-9

[ 中文名 ]:
益棉磷

[ 英文名 ]:
Azinphos-ethyl

[中文别名 ]:

[英文别名 ]:

益棉磷物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
444.7±55.0 °C at 760 mmHg

[ 熔点 ]:
53ºC

[ 分子式 ]:
C12H16N3O3PS2

[ 分子量 ]:
345.378

[ 闪点 ]:
222.7±31.5 °C

[ 精确质量 ]:
345.037079

[ PSA ]:
133.44000

[ LogP ]:
3.61

[ 蒸汽压 ]:
0.0±1.1 mmHg at 25°C

[ 折射率 ]:
1.651

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

益棉磷MSDS

益棉磷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TD8400000
CHEMICAL NAME :
Phosphorodithioic acid, O,O-diethyl ester, S-ester with 3-(mercaptomethyl)- 1,2,3-benzotriazin-4(3H)-one
CAS REGISTRY NUMBER :
2642-71-9
BEILSTEIN REFERENCE NO. :
0297468
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C12-H16-N3-O3-P-S2
MOLECULAR WEIGHT :
345.40
WISWESSER LINE NOTATION :
T66 BNNNVJ D1SPS&O2&O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ARSIM* Agricultural Research Service, USDA Information Memorandum. (Beltsville, MD 20705) Volume(issue)/page/year: 20,2,1966
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
390 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R., Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971 Volume(issue)/page/year: -,16,1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,24,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7500 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,24,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
12 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,45,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
34400 ug/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 11,49,1967 *** REVIEWS *** TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 51,123,1974 TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 63,1,1976
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益棉磷安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H300-H311-H410

[ 警示性声明 ]:
P273-P280-P301 + P310 + P330-P302 + P352 + P312-P391-P501

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T+: Very toxic;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
24-28-50/53

[ 安全声明 (欧洲) ]:
S28-S36/37-S45-S60-S61

[ 危险品运输编码 ]:
2783

[ RTECS号 ]:
TD8400000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(a)

益棉磷上下游产品

益棉磷制备

由邻氨苯甲酸甲酯经重氮化、环合、羟甲基化、氯甲基化、缩合而得。

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益棉磷文献

Characterization of P-S bond hydrolysis in organophosphorothioate pesticides by organophosphorus hydrolase.

Arch. Biochem. Biophys. 318(1) , 59-64, (1995)

The extensive use of organophosphorothioate insecticides in agriculture has resulted in the risk of environmental contamination with a variety of broadly based neurotoxins that inhibit the acetylcholi...

Performance of two monoclonal immunoassays in mixtures of cross-reacting dithiophosphorus pesticides

Talanta 74(1) , 52-8, (2007)

A statistical approach for the analysis of complex samples by immunoassay is proposed in this article. Two enzyme-linked immunosorbent assays (ELISAs), one of them in the conjugate-coated format and t...

Ethylazinphos interaction with membrane lipid organization induces increase of proton permeability and impairment of mitochondrial bioenergetic functions.

Toxicol. Appl. Pharmacol. 175(3) , 209-16, (2001)

Ethylazinphos increases the passive proton permeability of lipid bilayers reconstituted with dipalmitoylphosphatidylcholine (DPPC) and mitochondrial lipids. A sharp increase of proton permeability is ...


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相关化工产品/化学物质:

推荐生产厂家/供应商:

公司名:上海吉至生化科技有限公司

区域:上海市奉贤区

价格:
¥778.0/1ml

联系人:刘佳

产品详情:乙基古硫磷标准溶液


公司名:上海阿拉丁生化科技股份有限公司

区域:上海市浦东新区

价格:
¥需询单/1mg ¥需询单/1g ¥需询单/1g ¥需询单/1g

联系人:阿拉丁李高志

产品详情:乙基古硫磷标准溶液


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