< 生产厂家价格 >

(1S,2S)-(-)-1,2-二苯基乙二胺

(1S,2S)-(-)-1,2-二苯基乙二胺用途

【用途一】
广泛用于不对称合成及光学拆分，如烯烃的不对称羟基化反应、不对称醇醛缩合反应、不对称Diels-Alder反应、羰基的不对称烯丙基化反应、光学活性的丙二烯基醇和丙炔基醇的合成、不带官能团烯烃的不对称环氧化反应以及联萘酚的拆分等。

点击显示

(1S,2S)-(-)-1,2-二苯基乙二胺名称

[ CAS 号 ]:
29841-69-8

[ 中文名 ]:
(1S,2S)-(-)-1,2-二苯基乙二胺

[ 英文名 ]:
(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine

[中文别名 ]:

[英文别名 ]:

(1S,2S)-(−)-1,2-Diphenylethylenediamine
1,2-Ethanediamine, 1,2-diphenyl-, (1S,2S)-
(1S,2S)-(-)-1,2-Diphenylethylenediamine
(1R,2R)-(+)-1,2-Diphenylethylenediamine
(1S,2S)-1,2-diamino-1,2-diphenylethane
(S,S)-1,2-diphenyl-1,2-ethanodiamine
(S,S)-1,2-diphenylethylenediamine
(1R,2R)-1,2-Diphenylethan-1,2-diamin
(1R,2R)-1,2-Diphenylethylenediamine
(S,S)-1,2-diphenyl-1,2-diaminoethane

(1S,2S)-(-)-1,2-二苯基乙二胺物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
353.9±37.0 °C at 760 mmHg

[ 熔点 ]:
81-84ºC

[ 分子式 ]:
C₁₄H₁₆N₂

[ 分子量 ]:
212.290

[ 闪点 ]:
199.9±26.0 °C

[ 精确质量 ]:
212.131348

[ PSA ]:
52.04000

[ LogP ]:
1.60

[ 外观性状 ]:
白色至淡黄色晶体粉末

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.620

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
水溶性：微溶；可溶于：甲苯,甲醇

(1S,2S)-(-)-1,2-二苯基乙二胺MSDS

详细MSDS(安全技术说明书)

(1S,2S)-(-)-1,2-二苯基乙二胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2942000000

(1S,2S)-(-)-1,2-二苯基乙二胺上下游产品

(1S,2S)-(-)-1,2-二苯基乙二胺上游产品

(1S,2S)-(-)-1,2-二苯基乙二胺下游产品

(1S,2S)-(-)-1,2-二苯基乙二胺海关

[ 海关编码 ]: 2921590090

[ 中文概述 ]:
2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

(1S,2S)-(-)-1,2-二苯基乙二胺文献

Multiple UDP-glucuronosyltransferases in human liver microsomes glucuronidate both R- and S-7-hydroxywarfarin into two metabolites.

Arch. Biochem. Biophys. 564 , 244-53, (2014)

The widely used anticoagulant Coumadin (R/S-warfarin) undergoes oxidation by cytochromes P450 into hydroxywarfarins that subsequently become conjugated for excretion in urine. Hydroxywarfarins may mod...

NMDA receptor affinities of 1,2-diphenylethylamine and 1-(1,2-diphenylethyl)piperidine enantiomers and of related compounds.

Bioorg. Med. Chem. 17 , 3456-62, (2009)

We resolved 1,2-diphenylethylamine (DPEA) into its (S)- and (R)-enantiomer and used them as precursors for synthesis of (S)- and (R)-1-(1,2-diphenylethyl)piperidine, flexible homeomorphs of the NMDA c...

Analysis of leucine enkephalin by high-performance liquid chromatography using enzymatic derivatization by tyrosinase and electrochemical or fluorescence detection.

J. Pharm. Biomed. Anal. 19(6) , 855-64, (1999)

Two tyrosine specific, HPLC methods with either electrochemical (HPLC-ED) or fluorescence (HPLC-FL) detection are described for leucine-enkephalin (LE) in cerebrospinal fluid (CSF). Both approaches in...

更多文献