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N-(苄羰氧基)羟基胺

N-(苄羰氧基)羟基胺用途

用于Diels-Alder 反应，应用实例如下图所示：

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N-(苄羰氧基)羟基胺名称

[ CAS 号 ]:
3426-71-9

[ 中文名 ]:
N-(苄羰氧基)羟基胺

[ 英文名 ]:
Benzyl hydroxycarbamate

[中文别名 ]:

[英文别名 ]:

Carbamic acid,hydroxy-,phenylmethyl ester
N-Hydroxycarbamic Acid Benzyl Ester
N-Z-Hydroxylamine,Benzyl N-hydroxycarbamate
N-carbobenzoxyhydroxylamine
N-(Benzyloxycarbonyl)hydroxylamine
Carbamic acid, N-hydroxy-, phenylmethyl ester
N-Z-Hydroxylamine
Benzyl hydroxycarbamate
N-Cbz-hydroxylamine
MFCD00010642

N-(苄羰氧基)羟基胺物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
373.4±21.0 °C at 760 mmHg

[ 熔点 ]:
65-70 °C(lit.)

[ 分子式 ]:
C₈H₉NO₃

[ 分子量 ]:
167.162

[ 闪点 ]:
179.6±22.1 °C

[ 精确质量 ]:
167.058243

[ PSA ]:
58.56000

[ LogP ]:
1.37

[ 外观性状 ]:
固体;White to Light yellow to Light orange powder to crystal

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.560

[ 储存条件 ]:
2-8°C

N-(苄羰氧基)羟基胺MSDS

N-(苄羰氧基)羟基胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: FB1600000

CHEMICAL NAME :: Carbamic acid, hydroxy-, benzyl ester

CAS REGISTRY NUMBER :: 3426-71-9

BEILSTEIN REFERENCE NO. :: 1074034

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C8-H9-N-O3

MOLECULAR WEIGHT :: 167.18

WISWESSER LINE NOTATION :: QMVO1R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Escherichia coli

DOSE/DURATION :: 800 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 151,201,1985

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N-(苄羰氧基)羟基胺安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 安全声明 (欧洲) ]:
S22-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
FB1600000

[ 海关编码 ]:
2924299090

N-(苄羰氧基)羟基胺合成路线

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N-(苄羰氧基)羟基胺上游产品

N-(苄羰氧基)羟基胺下游产品

N-(苄羰氧基)羟基胺海关

[ 海关编码 ]: 2924299090

[ 中文概述 ]:
2924299090. 其他环酰胺（包括环氨基甲酸酯）（包括其衍生物以及他们的盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

N-(苄羰氧基)羟基胺文献

Inhibitors of bacterialN-succinyl-l,l-diaminopimelic acid desuccinylase (DapE) and demonstration of in vitro antimicrobial activity

Bioorg. Med. Chem. Lett. 19 , 6350-2, (2009)

A screen biased toward compounds containing zinc-binding groups (ZBG’s) delivered a number of micromolar inhibitors of DapE from Haemophilus influenzae, including l-captopril (IC 50 = 3.3 μM, K i = 1....

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